Zinc(II) and cadmium(II) complexes based on 2-(3,5-dimethyl-1H-pyrazol-1-yl)-6-(4-methoxyphenyl)pyrimidine-4-carboxylic acid: Synthesis, structure and luminescence

Zinc(II) and cadmium(II) complexes based on 2-(3,5-dimethyl-1H-pyrazol-1-yl)-6-(4-methoxyphenyl)pyrimidine-4-carboxylic acid: Synthesis, structure and luminescence Научная публикация

Журнал

Inorganic Chemistry Communications
ISSN: 1387-7003

Вых. Данные

Год: 2011, Том: 14, Номер: 5, Страницы: 749-752 Страниц : DOI: 10.1016/j.inoche.2011.02.027

Ключевые слова

Pyrazole; Pyrimidine; Carboxylate; Zinc(II); Cadmium(II); Luminescence

Авторы

Bushuev Mark B. ^1,2 , Krivopalov Viktor P. ³ , Nikolaenkova Elena B. ³ , Pervukhina Natalia V. ¹ , Naumov Dmitrii Yu ¹ , Rakhmanova Marianna I. ¹

Организации

1	(Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

Zinc(II) and cadmium(II) complexes. ZnL2 center dot 0.5H(2)O, ZnL2 center dot 2MeOH and CdL2 center dot 1.5H(2)O, based on a new hybrid compound, 2-(3,5-dimethyl-1H-pyrazol-1-yl)-6-(4-methoxyphenyl)pyrimidine-4-carboxylic acid (HL), have been synthesized. They are the first examples of metal complexes with pyrazolylpyrimidinecarboxylates. The complex ZnL2 center dot 2MeOH was structurally characterized. It has mononuclear structure; zinc atom is in the distorted octahedral coordination polyhedron 4N + 20 formed by donor atoms of two coordinated L- ions. The compounds HL, ZnL2 center dot 0.5H(2)O and CdL2 center dot 1.5H(2)O manifest bright blue photoluminescence. (C) 2011 Elsevier B.V. All rights reserved.

Bushuev M.B. , Krivopalov V.P. , Nikolaenkova E.B. , Pervukhina N.V. , Naumov D.Y. , Rakhmanova M.I.
Zinc(II) and cadmium(II) complexes based on 2-(3,5-dimethyl-1H-pyrazol-1-yl)-6-(4-methoxyphenyl)pyrimidine-4-carboxylic acid: Synthesis, structure and luminescence
Inorganic Chemistry Communications. 2011. V.14. N5. P.749-752. DOI: 10.1016/j.inoche.2011.02.027 WOS Scopus РИНЦ

Опубликована в печати:

1 мая 2011 г.

Web of science	WOS:000290460800034
Scopus	2-s2.0-79954423428
РИНЦ	17003199
OpenAlex	W2068370519