Effect of nucleophile on the activation parameters of transesterification of 4-nitrophenyl benzoates Научная публикация
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Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
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| Вых. Данные | Год: 2010, Том: 46, Номер: 3, Страницы: 326-330 Страниц : 5 DOI: 10.1134/S1070428010030048 | ||
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Реферат:
Activation parameters of the reaction of 4-nitrophenyl benzoates with benzenethiol in the presence of potassium carbonate in dimethylformamide were determined. The entropies of activation for the reactions of unsubstituted 4-nitrophenyl benzoate and 4-nitrophenyl benzoates having donor substituents are positive. The relative contributions of the enthalpy and entropy of activation to the Gibbs energy of activation are discussed. Variation of the activation parameters upon replacement of benzenethiol by 4-chlorophenol is analyzed.
Библиографическая ссылка:
Os'kina I.A.
, Vlasov V.M.
Effect of nucleophile on the activation parameters of transesterification of 4-nitrophenyl benzoates
Russian Journal of Organic Chemistry. 2010. V.46. N3. P.326-330. DOI: 10.1134/S1070428010030048 WOS Scopus РИНЦ
Effect of nucleophile on the activation parameters of transesterification of 4-nitrophenyl benzoates
Russian Journal of Organic Chemistry. 2010. V.46. N3. P.326-330. DOI: 10.1134/S1070428010030048 WOS Scopus РИНЦ
Даты:
| Опубликована в печати: | 1 мар. 2010 г. |
| Опубликована online: | 24 апр. 2010 г. |
Идентификаторы:
| Web of science | WOS:000277012800004 |
| Scopus | 2-s2.0-77952510459 |
| РИНЦ | 15317706 |
| OpenAlex | W2094049632 |