High-spin complex [FeL2(NCS)(2)]center dot H2O [L=3,5-di(pyrimidin-2-yl)-4H-1,2,4-triazol-4-amine]: Synthesis and properties

High-spin complex [FeL2(NCS)(2)]center dot H2O [L=3,5-di(pyrimidin-2-yl)-4H-1,2,4-triazol-4-amine]: Synthesis and properties Научная публикация

Журнал

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Вых. Данные

Год: 2010, Том: 80, Номер: 8, Страницы: 1703-1709 Страниц : DOI: 10.1134/S1070363210080220

Авторы

Bushuev M. B. ^1,2 , Krivopalov V. P. ³ , Daletskii V. A. ¹ , Varnek V. A. ¹ , Sheludyakova L. A. ^1,2 , Yushina I. V. ¹ , Shkurko O. P. ³

Организации

1	(Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk, Russia

Complex [FeL2(NCS)(2)]center dot H2O (L = 3,5-di(pyrimidin-2-yl)-4H-1,2,4-triazol-4-amine) was prepared as the first example of complex compounds of transition metals with 3,5-di(pyrimidin-2-yl)-4H-1,2,4-triazol-4-amines. The coordination core of the iron atom is a distorted octahedron FeN6. In the range 80-300 K the complex is high-spin, mu(eff) similar to 5.3 MB. The parameter of the crystal field splitting, 10Dq, for [FeL2(NCS)(2)]center dot H2O is similar to 10800 cm(-1).

Bushuev M.B. , Krivopalov V.P. , Daletskii V.A. , Varnek V.A. , Sheludyakova L.A. , Yushina I.V. , Shkurko O.P.
High-spin complex [FeL2(NCS)(2)]center dot H2O [L=3,5-di(pyrimidin-2-yl)-4H-1,2,4-triazol-4-amine]: Synthesis and properties
Russian Journal of General Chemistry. 2010. V.80. N8. P.1703-1709. DOI: 10.1134/S1070363210080220 WOS Scopus РИНЦ

Опубликована в печати:	1 авг. 2010 г.
Опубликована online:	22 сент. 2010 г.

Web of science	WOS:000282090800022
Scopus	2-s2.0-78149434329
РИНЦ	16715775
OpenAlex	W2018836397