Synthesis and characterization of polyimides based on novel isomeric perfluorinated naphthylenediamines

Synthesis and characterization of polyimides based on novel isomeric perfluorinated naphthylenediamines Научная публикация

Журнал

Journal of Fluorine Chemistry
ISSN: 0022-1139

Вых. Данные

Год: 2009, Том: 130, Номер: 8, Страницы: 733-741 Страниц : DOI: 10.1016/j.jfluchem.2009.05.019

Ключевые слова

Fluorinated polyimides; Polyimide properties; Diaminohexafluoronaphthalenes; MALDI-TOF MS

Авторы

Shundrina Inna K. ¹ , Vaganova Tamara A. ¹ , Kusov Soltan Z. ¹ , Rodionov Vladimir I. ¹ , Karpova Elena V. ¹ , Koval Vladimir V. ² , Gerasimova Yulia V. ² , Malykhin Evgenij V. ¹

Организации

1	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Inst Chem Biol & Fundamental Med, Siberian Branch, Novosibirsk 630090, Russia

Novel highly fluorinated polyimides containing hexafluoronaphthylene fragment in the main chain were prepared by the two-stage polymerization of 2,7- and 2,6-diaminohexafluoronaphthalenes with 4,4'-oxydiphthalic anhydride: polycondensation in a solution at 80 degrees C followed by high-temperature solid-state chain extension. The influence of hexafluoronaphthylene fragment isomerism on the key polyimide features - molecular weight. thermal stability, solubility, optical properties - was characterized. Polyimides based on 2,7-diaminohexafluoronaphthalene or easily accessible mixture of isomeric diamines formed the flexible, transparent, and thermostable films. (C) 2009 Elsevier B.V. All rights reserved.

Shundrina I.K. , Vaganova T.A. , Kusov S.Z. , Rodionov V.I. , Karpova E.V. , Koval V.V. , Gerasimova Y.V. , Malykhin E.V.
Synthesis and characterization of polyimides based on novel isomeric perfluorinated naphthylenediamines
Journal of Fluorine Chemistry. 2009. V.130. N8. P.733-741. DOI: 10.1016/j.jfluchem.2009.05.019 WOS Scopus РИНЦ

Опубликована в печати:

1 авг. 2009 г.

Web of science	WOS:000268938200007
Scopus	2-s2.0-67650526402
РИНЦ	13614130
OpenAlex	W2000778535