Polyvalent perfluoroorgano- and selected polyfluoroorgano-halogen(III and V) compounds

Polyvalent perfluoroorgano- and selected polyfluoroorgano-halogen(III and V) compounds Научная публикация

Журнал

Journal of Fluorine Chemistry
ISSN: 0022-1139

Вых. Данные

Год: 2008, Том: 129, Номер: 6, Страницы: 459-473 Страниц : 15 DOI: 10.1016/j.jfluchem.2008.04.001

Ключевые слова

polyvalent iodine compounds; polyvalent bromine compounds; perfluoroalkyl; perfluoroaryl; perfluoroalkenyl; perfluoroalkynyl; onium cations; NMR; structure

Авторы

Frohn Hermann-Josef ¹ , Hirschberg Markus E. ¹ , Wenda Andre ¹ , Bardin Vadim V. ²

Организации

1	(Данные Web of science) Univ Duisburg Essen, D-47048 Duisburg, Germany
2	(Данные Web of science) SB RAS, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

This review compiles important aspects of the chemistry of polyvalent perfluoroorganohalogen(III and V) compounds of the last three decades and reports on distinctions which are worth mentioning in comparison with non-fluorinated polyvalent organohalogen(III and V) analogues. Besides general synthetic paths to neutral (R(F)HalX(2), (R(F))(2)IX, (R(F))(3)I, and R(F)HalX(4)), cationic ([R(F)(R')Hal]Y and [R(F)(R')HalF(2)]Y), and anionic (M[R(F)HalX(3)] and M[(R(F))(2)HalX(2)]) derivatives of iodine and bromine, transformations at the halogen centre of those polyvalent compounds and selected applications and their use as reagents are referred. Trends of (19)F and (13)C NMR spectroscopic properties of prototypes of polyvalent perfluoroorgano-iodine and -bromine compounds are compiled and interpreted. Structural features of characteristic perfluoroalkyl-, pentafluorophenyliodine(III and V), and few -bromine(III) compounds are presented and compared. (C) 2008 Elsevier B.V. All rights reserved.

Frohn H-J. , Hirschberg M.E. , Wenda A. , Bardin V.V.
Polyvalent perfluoroorgano- and selected polyfluoroorgano-halogen(III and V) compounds
Journal of Fluorine Chemistry. 2008. V.129. N6. P.459-473. DOI: 10.1016/j.jfluchem.2008.04.001 WOS Scopus РИНЦ

Опубликована в печати:

1 июн. 2008 г.

Web of science	WOS:000257604800001
Scopus	2-s2.0-44649126636
РИНЦ	13587259
OpenAlex	W2045907296