Fe(II) complex with chiral pyrazolylquinoline L and Fe(II), Co(II), and Cu(II) complexes with achiral pyrazolylquinoline L-1: Synthesis and properties. the crystal structures of [(MLCl2)-Cl-1] (M = Fe, Co, and Cu)

Fe(II) complex with chiral pyrazolylquinoline L and Fe(II), Co(II), and Cu(II) complexes with achiral pyrazolylquinoline L-1: Synthesis and properties. the crystal structures of [(MLCl2)-Cl-1] (M = Fe, Co, and Cu) Научная публикация

Журнал

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Вых. Данные

Год: 2008, Том: 34, Номер: 4, Страницы: 278-285 Страниц : 8 DOI: 10.1134/S1070328408040076

Авторы

Savel'eva Z.A. , Glinskaya L.A. , Klevtsova R.F. , Popov S.A. , Tkachev A.V. , Semikolenova N.V. , Zakharov V.A. , Larionov S.V.

Организации

1	(Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhtsov Inst Organ Chem, Novosibirsk, Russia
3	(Данные Web of science) Russian Acad Sci, Siberian Div, Boreskov Inst Catalysis, Novosibirsk 630090, Russia

The complexes FeLCl2 (I), [(FeLCl2)-Cl-1] (II), [(CoLCl2)-Cl-1] (III), and [(CuLCl2)-Cl-1] (IV) (where L and L-1 are chiral and achiral pyrazolylquinolines, respectively) were obtained. Complexes II-IV were structurally characterized by single-crystal X-ray diffraction analysis. Crystals of complexes II and III are triclinic (space group P) and crystals of complex IV are monoclinic (space group P2(1)/n). Structures II-IV are built from discrete mononuclear acentric molecules. In these complexes, the M2+ ion (M = Fe, Co, and Cu) coordinates two N atoms of the bidentate chelating ligand L-1 and two Cl atoms. The coordination cores MCl2N2 are distorted tetrahedra. For complexes I and II, mu(eff) = 5.05 and 5.07 mu(B), respectively, correspond to the high-spin configuration d(6). For complex III, mu(eff) = 4.51 mu(B) (high-spin configuration d(7)) and for complex IV, mu(eff) = 1.80 mu(B) (configuration d(9)).

Savel'eva Z.A. , Glinskaya L.A. , Klevtsova R.F. , Popov S.A. , Tkachev A.V. , Semikolenova N.V. , Zakharov V.A. , Larionov S.V.
Fe(II) complex with chiral pyrazolylquinoline L and Fe(II), Co(II), and Cu(II) complexes with achiral pyrazolylquinoline L-1: Synthesis and properties. the crystal structures of [(MLCl2)-Cl-1] (M = Fe, Co, and Cu)
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2008. V.34. N4. P.278-285. DOI: 10.1134/S1070328408040076 WOS Scopus РИНЦ

Савельева З.А. , Глинская Л.А. , Клевцова Р.Ф. , Попов С.А. , Ткачев А.В. , Семиколенова Н.В. , Захаров В.А. , Ларионов С.В.
Синтез и свойства комплекса Fe(ii) с хиральным пиразолилхинолином l и комплексов Fe(ii), Co(ii), Cu(ii) с ахиральным пиразолилхинолином l1. кристаллическая структура соединений [ml1cl2] (m = Fe, Co,Cu)
Координационная химия (RUSS J COORD CHEM+). 2008. Т.34. №4. С.285-292. РИНЦ

Опубликована в печати:	1 апр. 2008 г.
Опубликована online:	4 мая 2008 г.

Web of science	WOS:000255586800007
Scopus	2-s2.0-43249130508
РИНЦ	13566398
OpenAlex	W2047761127