Reductive activation of arenes 21. Reaction of products of two-electron reduction of arenecarbonitriles by alkali metals in liquid ammonia with bromo- and dibromoalkanes Научная публикация
| Журнал |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Вых. Данные | Год: 2006, Том: 55, Номер: 6, Страницы: 981-986 Страниц : DOI: 10.1007/s11172-006-0366-0 | ||||||
| Ключевые слова | aromatic nitrites; reductive alkylation; cyanocyclohexadienyl anions; l-alkyl-l-cyanocyclohexa-2,5-dienes; 1-(omega-bromoalkyl)-l-cyanocyclohexa-2,5-dienes | ||||||
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Реферат:
Reductive alkylation of benzonitrile, ortho-, meta-, para-tolunitriles, and 1-naphthonitrile by sequential action of alkali metal and alkyl bromide in liquid ammonia results in corresponding alkylarenes and 1-alkyl-1-cyanocyclohexa-2,5-dienes. The experimental conditions for target synthesis of the specified products are found. A method of synthesis of 1-(omega-bromoalkyl)-1-cyanocyclohexa-2,5-dienes based on the interaction of two-electronic reduction products of aromatic nitriles with alpha,omega-dibromoalkanes Br(CH2)(n)Br (n = 3-5) is developed.
Библиографическая ссылка:
Vaganova T.A.
, Panteleeva E.V.
, Yuferov P.S.
, Rebitva Y.V.
, Shteingarts V.D.
Reductive activation of arenes 21. Reaction of products of two-electron reduction of arenecarbonitriles by alkali metals in liquid ammonia with bromo- and dibromoalkanes
Russian Chemical Bulletin. 2006. V.55. N6. P.981-986. DOI: 10.1007/s11172-006-0366-0 WOS Scopus РИНЦ
Reductive activation of arenes 21. Reaction of products of two-electron reduction of arenecarbonitriles by alkali metals in liquid ammonia with bromo- and dibromoalkanes
Russian Chemical Bulletin. 2006. V.55. N6. P.981-986. DOI: 10.1007/s11172-006-0366-0 WOS Scopus РИНЦ
Даты:
| Опубликована в печати: | 1 июн. 2006 г. |
Идентификаторы:
| Web of science | WOS:000242652000008 |
| Scopus | 2-s2.0-33750718171 |
| РИНЦ | 13524130 |
| OpenAlex | W2126508608 |