Molecular complexes of octafluoronaphthalene with catenated chalcogen-nitrogen compounds C6H5-X-N=S=N-SiMe3 (X = S, Se)

Molecular complexes of octafluoronaphthalene with catenated chalcogen-nitrogen compounds C6H5-X-N=S=N-SiMe3 (X = S, Se) Научная публикация

Журнал

Journal of Fluorine Chemistry
ISSN: 0022-1139

Вых. Данные

Год: 2006, Том: 127, Номер: 3, Страницы: 437-442 Страниц : 6 DOI: 10.1016/j.jfluchem.2005.11.021

Ключевые слова

octafluoronaphthalene; chalcogen-nitrogen compounds; molecular complexes; pi-stacking interactions; X-ray structure determination

Авторы

Makarov A.Yu. ¹ , Lork E. ² , Mews R. ² , Zibarev A.V. ^1,3

Организации

1	(Данные Web of science) Russian Acad Sci, Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Univ Bremen, Inst Inorgan & Phys Chem, D-28334 Bremen, Germany
3	(Данные Web of science) Novosibirsk State Univ, Dept Phys, Novosibirsk 630090, Russia

Mismatched molecular 1:1 complexes of C10F8 with catenated chalcogen-nitrogen compounds C6H5-X-N=S=N-SiMe3 (X=S, Se) were prepared and characterized by X-ray crystallography. The complexes provide examples of structurally non-rigid polyheteroatom molecules involved in non-covalent arene-polyfluoroarene pi-stacking interactions. In going from homocrystals to the co-crystals, the molecular Z, E configuration of the catenated compounds changes from noticeibly non-planar to perfectly planar, i.e. C10F8 acts as "molecular iron". On the other hand, C10H8 does not produce complexes with C6F5-X-N=S=N-SiMe3 (X = S, Se). (c) 2006 Elsevier B.V. All rights reserved.

Makarov A.Y. , Lork E. , Mews R. , Zibarev A.V.
Molecular complexes of octafluoronaphthalene with catenated chalcogen-nitrogen compounds C6H5-X-N=S=N-SiMe3 (X = S, Se)
Journal of Fluorine Chemistry. 2006. V.127. N3. P.437-442. DOI: 10.1016/j.jfluchem.2005.11.021 WOS Scopus РИНЦ

Опубликована в печати:

1 мар. 2006 г.

Web of science	WOS:000236926300019
Scopus	2-s2.0-33645379466
РИНЦ	13505945
OpenAlex	W2129442095