Synthesis of optically active, cyclic alpha-hydroxy ketones and 1,2-diketones from verbenone epoxide

Synthesis of optically active, cyclic alpha-hydroxy ketones and 1,2-diketones from verbenone epoxide Научная публикация

Журнал

Helvetica Chimica Acta
ISSN: 0018-019X , E-ISSN: 1522-2675

Вых. Данные

Год: 2006, Том: 89, Номер: 3, Страницы: 507-514 Страниц : DOI: 10.1002/hlca.200690052

Авторы

Il'ina IV , Volcho KP , Korchagina DV , Barkhash VA , Salakhutdinov NF

Организации

1	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

The reactivity of verbenone epoxide (5), a terpenoid from the pinane series, towards different aliphatic and aromatic aldehydes in the presence of natural montmorillonite (askanite-bentonite) clay has been studied. A series of mechanistically different transformations afforded a number of new, optically active, polyfunctional compounds (7, 8, 10 - 14, 16). These products are potentially interesting synthons in asymmetric synthesis.

Il'ina I. , Volcho K. , Korchagina D. , Barkhash V. , Salakhutdinov N.
Synthesis of optically active, cyclic alpha-hydroxy ketones and 1,2-diketones from verbenone epoxide
Helvetica Chimica Acta. 2006. V.89. N3. P.507-514. DOI: 10.1002/hlca.200690052 WOS Scopus РИНЦ

Опубликована в печати:

1 мар. 2006 г.

Web of science	WOS:000236535500013
Scopus	2-s2.0-33645580391
РИНЦ	13505982
OpenAlex	W2027871678