Synthesis and crystal and molecular structure of the complex [Cu(HL)Cl](2)[CuCl4], where HL is optically active terpenic (1S,3S,6R)-3-[N-(3-aminopropyl)aminol-4-caranone (E)-oxime

Synthesis and crystal and molecular structure of the complex [Cu(HL)Cl](2)[CuCl4], where HL is optically active terpenic (1S,3S,6R)-3-[N-(3-aminopropyl)aminol-4-caranone (E)-oxime Научная публикация

Журнал

Russian Journal of Inorganic Chemistry
ISSN: 0036-0236

Вых. Данные

Год: 2005, Том: 50, Номер: 5, Страницы: 711-714 Страниц : 4

Авторы

Larionov S.V. ¹ , Savel'eva Z.A. ¹ , Glinskaya L.A. ¹ , Klevtsova R.F. ¹ , Ikorskii V.N. ¹ , Bizyaev S.N. ² , Tkachev A.V. ²

Организации

1	Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 3
2	Vorozhtsov Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 9

A new paramagnetic compound [Cu(HL)Cl](2)[CuCl4], where HL is optically active (1S,3S,6R)-3-[N-(3-aminopropyl)amino]-4-caranone (E)-oxime, was synthesized. Its crystal and molecular structure was determined by X-ray diffraction. The compound consists of complex cations [Cu(HL)Cl](+) and outer-sphere tetrahedral anions [CuCl4](2-). In the complex cation, the Cu2+, ion coordinates three N atoms (Cu-N 1.967(5)-2.029(5) A) of the tridentate ring-forming ligand HL and one Cl atom (Cu-Cl 2.281(2) angstrom). The coordination core CuN3Cl is a distorted square.

Larionov S.V. , Savel'eva Z.A. , Glinskaya L.A. , Klevtsova R.F. , Ikorskii V.N. , Bizyaev S.N. , Tkachev A.V.
Synthesis and crystal and molecular structure of the complex [Cu(HL)Cl](2)[CuCl4], where HL is optically active terpenic (1S,3S,6R)-3-[N-(3-aminopropyl)aminol-4-caranone (E)-oxime
Russian Journal of Inorganic Chemistry. 2005. V.50. N5. P.711-714. WOS Scopus РИНЦ

Ларионов С.В. , Савельева З.А. , Глинская Л.А. , Клевцова Р.Ф. , Икорский В.Н. , Бизяев С.Н. , Ткачев А.В.
СИНТЕЗ, КРИСТАЛЛИЧЕСКАЯ И МОЛЕКУЛЯРНАЯ СТРУКТУРА КОМПЛЕКСА [CU(HL)CL]2[CUCL4], ГДЕ HL - ОПТИЧЕСКИ АКТИВНЫЙ ТЕРПЕНОВЫЙ (E)-ОКСИМ (1S,3S,6R)-3-[N-(3-AМИНОПРОПИЛ)AМИНО]-4-КAPAНОНA)
Журнал неорганической химии. 2005. Т.50. №5. С.786-789. РИНЦ

Web of science	WOS:000229354600012
Scopus	2-s2.0-20444373011
РИНЦ	13497344