Structure and reactivity of the 1,10-phenanthroline complex with nitrenium cation

Structure and reactivity of the 1,10-phenanthroline complex with nitrenium cation Научная публикация

Журнал

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Вых. Данные

Год: 2004, Том: 40, Номер: 4, Страницы: 567-574 Страниц : 8 DOI: 10.1023/B:RUJO.0000036081.51473.c0

Авторы

Andreev RV ¹ , Borodkin GI ¹ , Gatilov YV ¹ , Shakirov MM ¹ , Shubin VG ¹

Организации

1	(Данные Web of science) Russian Acad Sci, Vorozhsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

According to the X-ray diffraction data, the cationic fragment in 1-amino-1,10-phenanthrolinium mesitylenesulfonate is a unidentate n-complex whose asymmetric structure is retained in solution. Quantum-chemical calculations by the AMI method and ab initio (6-31G 6-31G*, MP2/6-31G) give geometric parameters of the cation, which are similar to those determined experimentally. No dynamic processes involving intra- or intermolecular transfer of the NH2 group was observed up to 100degreesC by NMR spectroscopy. 1-Amino-1,10-phenanthrolinium cation does not react with 4-methylpyridine and 4-methyl-1,10-phenanthroline with transfer of the amino group, and it fails to react with mesitylene and anthracene at elevated temperature.

Andreev R. , Borodkin G. , Gatilov Y. , Shakirov M. , Shubin V.
Structure and reactivity of the 1,10-phenanthroline complex with nitrenium cation
Russian Journal of Organic Chemistry. 2004. V.40. N4. P.567-574. DOI: 10.1023/B:RUJO.0000036081.51473.c0 WOS Scopus РИНЦ

Андреев Р.В. , Бородкин Г.И. , Гатилов Ю.В. , Шакиров М.М. , Шубин В.Г.
Строение и реакционная способность комплекса 1,10-фенантролина с нитрений-катионом
Журнал органической химии (RUSS J ORG CHEM+). 2004. Т.40. №4. С.595-602. РИНЦ

Опубликована в печати:

1 апр. 2004 г.

Web of science	WOS:000222560400021
Scopus	2-s2.0-4043089748
РИНЦ	14462973
OpenAlex	W2045953930