Preparation of 1-X-2,2-difluoroethenylxenon(II) tetrafluoroborates [CF2=CXXe][BF4]

Preparation of 1-X-2,2-difluoroethenylxenon(II) tetrafluoroborates [CF2=CXXe][BF4] Научная публикация

Журнал

Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313

Вых. Данные

Год: 2003, Том: 629, Номер: 14, Страницы: 2465-2469 Страниц : DOI: 10.1002/zaac.200300224

Ключевые слова

noble gas chemistry; xenon-carbon compounds; polyfluoroalkenylboranes; xenodeborylation; polyfluoroalkylborate anions; NMR spectroscopy

Авторы

Frohn HJ , Bardin VV

Организации

1	(Данные Web of science) Univ Duisburg Gesamthsch, Inst Chem, D-47048 Duisburg, Germany
2	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, SB, Novosibirsk 630090, Russia

The new type of alkenylxenon(II) salts [CF2=CXXe] [BF4] (X = H, Cl, CF3) was prepared by reacting the corresponding alkenyldifluoroboranes CF2 = CXBF2 with XeF2 in 1,1,1,3,3-pentafluoropropane (PFP) at -60 degreesC. The alkenylxenon(II) salts were characterised by multinuclear NMR spectroscopy. The influence of the substituent X at C-1 on the stability of alkenylxenon(II) salts is discussed. Additionally the preparation of the potassium alkenyl-trifluoroborate salts K [CF2=CXBF3] and their transformation into the boranes CF2=CXBF2 by fluoride abstraction in PFP is reported.

Frohn H. , Bardin V.
Preparation of 1-X-2,2-difluoroethenylxenon(II) tetrafluoroborates [CF2=CXXe][BF4]
Zeitschrift fur Anorganische und Allgemeine Chemie. 2003. V.629. N14. P.2465-2469. DOI: 10.1002/zaac.200300224 WOS Scopus РИНЦ

Опубликована в печати:

1 дек. 2003 г.

Web of science	WOS:000188203600011
Scopus	2-s2.0-0347090478
РИНЦ	13437556
OpenAlex	W1974191764