Реферат: Nickel(II) and cobalt(II) complexes with optically active diaminodioxime (H2L, the derivative of 3-carene) of the compositions [Ni(H2L)NO3]NO3 (1), Ni(H2L)Cl-2 (II), [Ni(HL)]ClO4 (.) H2O (III), and Co(H2L)Cl-2 (IV), were synthesized. According to X-ray diffraction data, the structures of the paramagnetic compound I and diamagnetic complex III are ionic. In the cation of I, the distorted NiN4O2 octahedron is formed by the N atoms of the tetradentate cyclic ligand (H,L molecule) and by the O atoms of NO3- anion functioning as bidentate cyclic ligands. In the cation of III, the NiN4 coordination unit is a distorted square formed upon coordination of the tetradentate cyclic ligand, HL- anion. The data of magnetochemistry and UV-Vis, IR, and Raman spectroscopy suggest that paramagnetic complexes H and IV contain a distorted octahedral polyhedron MCl2N4 (M = Ni, Co).

Библиографическая ссылка: Larionov S. , Myachina L. , Glinskaya L. , Klevtsova R. , Sheludyakova L. , Tkachev A. , Bizyaev S.
Synthesis, structure, and properties of nickel(II) and cobalt(II) coordination compounds with optically active diaminodioxime (H2L) derived from 3-carene. Molecular and crystal structures of the [Ni(H2L)(NO3)]NO3 and [Ni(HL)]ClO4 center dot H2O complexes
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2003. V.29. N11. P.795-804. DOI: 10.1023/B:RUCO.0000003437.79753.d6 WOS Scopus РИНЦ

Оригинальная версия: Ларионов С.В. , Мячина Л.И. , Глинская Л.А. , Клевцова Р.Ф. , Шелудякова Л.А. , Ткачев А.В. , Бизяев С.Н.
Синтез, строение и свойства координационных соединений никеля(ii) и кобальта(ii) с оптически активным диаминодиоксимом (h 2l) -производным 3-карена. молекулярные и кристаллические структуры комплексов [Ni(H2L)(NO3)]NO3 и [Ni(HL)]ClO4 • H 2O
Координационная химия (RUSS J COORD CHEM+). 2003. Т.29. №11. С.857. РИНЦ

Даты:

Опубликована в печати:

1 нояб. 2003 г.

Идентификаторы:

Web of science	WOS:000186826400006
Scopus	2-s2.0-3543084596
РИНЦ	13437982
OpenAlex	W2020536331

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