Preparative electrochemical reduction of fluorinated benzonitriles

Preparative electrochemical reduction of fluorinated benzonitriles Научная публикация

Журнал

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Вых. Данные

Год: 2003, Том: 39, Номер: 2, Страницы: 212-218 Страниц : 7 DOI: 10.1023/A:1025588119221

Авторы

Efremova NV ¹ , Podryvanova LV ¹ , Vasil'eva NV ¹ , Starichenko VF ¹ , Shteingarts VD ¹

Организации

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Electrochemical reduction of fluorinated benzonitriles in aprotic media is accompanied by concurrent processes of dimerization and fragmentation of the corresponding anion-radicals. With 2-fluoro- and 3,4,5-trifluorobenzonitriles the defluorinated products can be obtained at direct electrochemical reduction; for the other compounds studied have been found mediators providing a possibility to obtain in high yield defluorinated products at preparative electrochemical reduction. A fundamental possibility was demonstrated of providing products by nucleophilic fluorine substitution by S-BN mechanism at electrochemical reduction of fluorinated benzonitriles in aprotic solvents in the presence of mediators.

Efremova N. , Podryvanova L. , Vasil'eva N. , Starichenko V. , Shteingarts V.
Preparative electrochemical reduction of fluorinated benzonitriles
Russian Journal of Organic Chemistry. 2003. V.39. N2. P.212-218. DOI: 10.1023/A:1025588119221 WOS Scopus РИНЦ

Ефремова Н.В. , Подрыванова Л.В. , Васильева Н.В. , Стариченко В.Ф. , Штейнгарц В.Д.
Препаративное электрохимическое восстановление фторированных бензонитрилов
Журнал органической химии (RUSS J ORG CHEM+). 2003. Т.39. №2. С.235-241. РИНЦ

Web of science	WOS:000183932200010
Scopus	2-s2.0-0041914070
РИНЦ	13427268
OpenAlex	W2953112744