Polyfluoroorganoboron-oxygen compounds. 1 - Polyfluorinated aryl(dihydroxy)boranes and tri(aryl)boroxins

Polyfluoroorganoboron-oxygen compounds. 1 - Polyfluorinated aryl(dihydroxy)boranes and tri(aryl)boroxins Научная публикация

Журнал

Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313

Вых. Данные

Год: 2002, Том: 628, Номер: 13, Страницы: 2827-2833 Страниц : 7 DOI: 10.1002/1521-3749(200213)628:13<2827::AID-ZAAC2827>3.0.CO;2-N

Ключевые слова

polyfluoroaryl(dihydroxy)boranes (polyfluorophenyl-boronic acids); tris(polyfluloroaryl)boroxins; dehydration; NMR spectroscopy

Авторы

Frohn H ¹ , Adonin NY ² , Bardin VV ² , Starichenko VF ²

Организации

1	(Данные Web of science) Univ Duisburg Gesamthsch, Fachgebiet Anorgan Chem, D-47048 Duisburg, Germany
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk, Russia

A general preparative procedure for polyfluorinated aryl(dihydroxy)boranes C6H5-nFnB(OH)(2) (n = 3 - 5) is described. Polyfluorinated aryl(dihydroxy)boranes are easily dehydrated to the corresponding tri(aryl)boroxins (C6H5-nFnBO)(3) by thermal or chemical treatment. The property of the acids C6H5-nFnB(OH)(2) to condensate depends on the number and on the position of the fluorine atoms in the aryl group. Examples of both classes of boron compounds were isolated as pure individuals and characterized by multinuclear NMR spectroscopy.

Frohn H. , Adonin N. , Bardin V. , Starichenko V.
Polyfluoroorganoboron-oxygen compounds. 1 - Polyfluorinated aryl(dihydroxy)boranes and tri(aryl)boroxins
Zeitschrift fur Anorganische und Allgemeine Chemie. 2002. V.628. N13. P.2827-2833. DOI: 10.1002/1521-3749(200213)628:13<2827::AID-ZAAC2827>3.0.CO;2-N WOS Scopus РИНЦ

Web of science	WOS:000180534500006
Scopus	2-s2.0-0036939933
РИНЦ	13413441
OpenAlex	W1510803058