Reductive activation of arenes: XIV. Effect of medium on the products ratio in the alkylation of nitrobenzene radical anion sodium salt

Reductive activation of arenes: XIV. Effect of medium on the products ratio in the alkylation of nitrobenzene radical anion sodium salt Научная публикация

Журнал

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Вых. Данные

Год: 2001, Том: 37, Номер: 12, Страницы: 1719-1722 Страниц : 4 DOI: 10.1023/A:1013969901048

Авторы

Selivanov B.A. ¹ , Shteingarts V.D. ¹

Организации

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

The product of nitrobenzene reduction by 1 equiv of sodium reacted with tert-butyl iodide in liquid ammonia and its mixtures with tetrahydrofuran and hexamethylphosphoramide to afford a mixture of compounds alkylated either by the functional group (N-alkylation) or at the benzene ring (C-alkylation). The ratio of N- and C-alkylation products decreases in the solvents series NH3-THF (5.7) > NH3 (1.0) > NH3-HMPA (0.6).

Selivanov B.A. , Shteingarts V.D.
Reductive activation of arenes: XIV. Effect of medium on the products ratio in the alkylation of nitrobenzene radical anion sodium salt
Russian Journal of Organic Chemistry. 2001. V.37. N12. P.1719-1722. DOI: 10.1023/A:1013969901048 WOS Scopus РИНЦ

Web of science	WOS:000174580600010
Scopus	2-s2.0-0035528730
РИНЦ	13386586
OpenAlex	W267018193