Skeletal Transformations of the Arylation Products of Perfluoro(1,2-diethylbenzocyclobutene) with Tetrafluorobenzenes in the Presence of SbF5

Skeletal Transformations of the Arylation Products of Perfluoro(1,2-diethylbenzocyclobutene) with Tetrafluorobenzenes in the Presence of SbF5 Научная публикация

Журнал

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Вых. Данные

Год: 2020, Том: 56, Номер: 3, Страницы: 429-435 Страниц : 7 DOI: 10.1134/S1070428020030100

Ключевые слова

perfluoro(1; 2-diethylcyclobutabenzene); tetrafluorobenzene; cation; skeletal transformations; antimony pentafluoride

Авторы

Mezhenkova T.V. ¹ , Sinyakov V.R. ¹ , Karpov V.M. ¹ , Zonov Ya.V. ^1,2

Организации

1	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2	Novosibirsk National Research State University, Novosibirsk, 630090 Russia

The reaction of perfluoro(1,2-diethylbenzocyclobutene) with 1,2,4,5-tetrafluorobenzene in SbF5, followed by hydrolysis, gave products resulting from expansion of the tetrafluorophenyl ring to cycloheptatriene. The title compound reacted with 1,2,3,5-tetrafluorobenzene to form products of opening of the four-membered ring. A similar reaction with 1,2,3,4-tetrafluorobenzene involved opening of the cyclobutane ring together with the formation of perfluoro(9,10-diethyl-9.10-dihydroanthracene) derivatives.

Mezhenkova T.V. , Sinyakov V.R. , Karpov V.M. , Zonov Y.V.
Skeletal Transformations of the Arylation Products of Perfluoro(1,2-diethylbenzocyclobutene) with Tetrafluorobenzenes in the Presence of SbF5
Russian Journal of Organic Chemistry. 2020. V.56. N3. P.429-435. DOI: 10.1134/S1070428020030100 WOS Scopus РИНЦ

Меженкова Т.В. , Синяков В.Р. , Карпов В.М. , Зонов Я.В.
Скелетные превращения продуктов арилирования перфтор-1,2-диэтилбензоциклобутена тетрафторбензолами в присутствии sbf5
Журнал органической химии (RUSS J ORG CHEM+). 2020. Т.56. №3. С.422-429. DOI: 10.31857/S0514749220030118 РИНЦ

Поступила в редакцию:	21 нояб. 2019 г.
Принята к публикации:	17 янв. 2020 г.
Опубликована в печати:	1 мар. 2020 г.
Опубликована online:	22 апр. 2020 г.

Web of science	WOS:000527931800010
Scopus	2-s2.0-85083672795
РИНЦ	43271384
OpenAlex	W3019318453