Reductive defluorination of perfluoroarenes by zinc in aqueous ammonia Научная публикация
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Journal of Fluorine Chemistry
ISSN: 0022-1139 |
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| Вых. Данные | Год: 1998, Том: 91, Номер: 1, Страницы: 21-23 Страниц : 3 DOI: 10.1016/S0022-1139(98)00194-8 | ||
| Ключевые слова | reductive defluorination; zinc; aqueous ammonia; perfluoroarenes; hexafluorobenzene; octafluorotoluenes; octafluoronaphthalene; decafluorobiphenyl | ||
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Реферат:
A very simple reductive system such as zinc in aqueous ammonia has been shown to be applicable for hydrodefluorination of some perfluoroarenes (hexafluorobenzene, octafluorotoluene, octafluoronaphthalene and decafluorobiphenyl) under mild conditions. In all cases an ammonia concentration effect has been observed. Moreover, for octafluoronaphthalene, the presence of NH4Cl is of importance and for decafluorobiphenyl this factor and the addition of an organic solvent to the aqueous ammonia are significant. (C) 1998 Elsevier Science S.A. All rights reserved.
Библиографическая ссылка:
Laev S.S.
, Shteingarts V.D.
Reductive defluorination of perfluoroarenes by zinc in aqueous ammonia
Journal of Fluorine Chemistry. 1998. V.91. N1. P.21-23. DOI: 10.1016/S0022-1139(98)00194-8 WOS Scopus РИНЦ
Reductive defluorination of perfluoroarenes by zinc in aqueous ammonia
Journal of Fluorine Chemistry. 1998. V.91. N1. P.21-23. DOI: 10.1016/S0022-1139(98)00194-8 WOS Scopus РИНЦ
Даты:
| Опубликована в печати: | 1 авг. 1998 г. |
Идентификаторы:
| Web of science | WOS:000075497400006 |
| Scopus | 2-s2.0-0032504353 |
| РИНЦ | 13299108 |
| OpenAlex | W4241879514 |