Reactions of polyfluoroaromatic compounds with electrophilic agents in the presence of tris(dialkylamino) phosphines .8. Replacement of fluorine by hydrogen in polyfluoroaromatic compounds Научная публикация
| Журнал |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Вых. Данные | Год: 1997, Том: 46, Номер: 8, Страницы: 1434-1436 Страниц : 3 DOI: 10.1007/BF02505680 | ||
| Ключевые слова | polyfluoroarenes; reduction; tris(diethylamino)phosphine | ||
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Реферат:
When reacted with P(NEt2)(3) and a proton donor, pentafluoropyridine, 3-chlorotetrafluoropyridine, pentafluorobenzonitrile, and octafluorotoluene yield products of replacement of the fluorine atom by hydrogen at position 4. This process is accompanied by the side reaction of aminodefluorination. In the case of 3-H-heptafluorotoluene and octafluoronaphthalene, aminodefluorination is the main reaction. Reactions of perfluoro-4-isopropyltoluene, 4-H-heptafluorotoluene, and 4-methylheptafluorotoluene do not occur under the above-mentioned conditions.
Библиографическая ссылка:
Bardin V.V.
Reactions of polyfluoroaromatic compounds with electrophilic agents in the presence of tris(dialkylamino) phosphines .8. Replacement of fluorine by hydrogen in polyfluoroaromatic compounds
Russian Chemical Bulletin. 1997. V.46. N8. P.1434-1436. DOI: 10.1007/BF02505680 WOS Scopus РИНЦ
Reactions of polyfluoroaromatic compounds with electrophilic agents in the presence of tris(dialkylamino) phosphines .8. Replacement of fluorine by hydrogen in polyfluoroaromatic compounds
Russian Chemical Bulletin. 1997. V.46. N8. P.1434-1436. DOI: 10.1007/BF02505680 WOS Scopus РИНЦ
Даты:
| Опубликована в печати: | 1 авг. 1997 г. |
Идентификаторы:
| Web of science | WOS:A1997YE52900013 |
| Scopus | 2-s2.0-0031495908 |
| РИНЦ | 13269433 |
| OpenAlex | W2335349394 |