Реферат: The solid-phase reaction of sodium percarbonate with brown coal was investigated. The results of determining the effect of a peroxide component of sodium percarbonate on an increase in the yield of humic acids as a result of the reaction are presented. It was found that the mechanism of radical oxidation makes a significant contribution to the course of the reaction. Changes in the structure of humic acids because of oxidation in the mechanochemical reaction of brown coal with sodium percarbonate were studied by IR spectroscopy and elemental analysis. An increase in the concentration of phenolic and carboxyl groups in the structure of humic acids from brown coal after the reaction was caused by the appearance of new groups as a result of oxidation and their release due to the destruction of stable complexes with metals.

Библиографическая ссылка: Skripkina T.S. , Bychkov A.L. , Tikhova V.D. , Lomovsky O.I.
Mechanochemical Solid-Phase Reactions of Humic Acids from Brown Coal with Sodium Percarbonate
Solid Fuel Chemistry. 2018. V.52. N6. P.356-360. DOI: 10.3103/S0361521918060101 WOS Scopus РИНЦ

Оригинальная версия: Скрипкина Т.С. , Бычков А.Л. , Тихова В.Д. , Ломовский О.И.
Твердофазные механохимические реакции гуминовых кислот бурого угля с перкарбонатом натрия
Химия твердого топлива. 2018. №6. С.16-20. DOI: 10.1134/S0023117718060117 РИНЦ

Даты:

Опубликована в печати:	1 нояб. 2018 г.
Опубликована online:	14 янв. 2019 г.

Идентификаторы:

Web of science	WOS:000455668000003
Scopus	2-s2.0-85060176436
РИНЦ	38664681
OpenAlex	W2909659107

Альметрики: