D/H ISOTOPE EFFECTS IN PI-COMPLEXES OF DEUTERATED HEXAMETHYLBENZENES WITH THE NITROSONIUM CATION Научная публикация
| Журнал |
BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE
ISSN: 1063-5211 |
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| Вых. Данные | Год: 1992, Том: 41, Номер: 9, Страницы: 1641-1645 Страниц : 5 DOI: 10.1007/BF00863586 | ||
| Ключевые слова | ISOTOPE EFFECTS; PI-COMPLEXES; C-13 NMR; NITROSONIUM CATION; HEXAMETHYLBENZENE | ||
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| Организации |
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Реферат:
The isotope effects of deuterium, manifested in the C-13 NMR spectra of complexes of deuterated hexamethylbenzenes C6(CD3)n.(CH3)6-n with the nitrosonium cation, have been studied. The small values observed for the isotopic perturbation are evidence of pi-bonding of the NO+ group to the hexamethylbenzene molecule. The applicability of an additive scheme of calculation of isotope effects for the ring carbon atoms of the complexes, based on the increments of replacement of the CH3 group by CD3 in hexamethylbenzene, has been demonstrated.
Библиографическая ссылка:
Borodkin G.I.
, Elanov I.R.
, Shakirov M.M.
, Shubin V.G.
D/H ISOTOPE EFFECTS IN PI-COMPLEXES OF DEUTERATED HEXAMETHYLBENZENES WITH THE NITROSONIUM CATION
BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE. 1992. V.41. N9. P.1641-1645. DOI: 10.1007/BF00863586 WOS Scopus
D/H ISOTOPE EFFECTS IN PI-COMPLEXES OF DEUTERATED HEXAMETHYLBENZENES WITH THE NITROSONIUM CATION
BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE. 1992. V.41. N9. P.1641-1645. DOI: 10.1007/BF00863586 WOS Scopus
Даты:
| Опубликована в печати: | 1 сент. 1992 г. |
Идентификаторы:
| Web of science | WOS:A1992LE58700004 |
| Scopus | 2-s2.0-34249841790 |
| OpenAlex | W1969341463 |