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Verdazyl Radical Building Blocks: Synthesis, Structure, and Sonogashira Cross-Coupling Reactions Научная публикация

Журнал European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690
Вых. Данные Год: 2018, Том: 2018, Номер: 34, Страницы: 4802-4811 Страниц : 10 DOI: 10.1002/ejoc.201701783
Ключевые слова Verdazyl radicals; Nitrogen heterocycles; Cross-coupling; Density functional calculations
Авторы Petunin Pavel V. 1,2 , Martynko Ekaterina A. 1 , Trusova Marina E. 1 , Kazantsev Maxim S. 2,3 , Rybalova Tatyana V. 2,3 , Valiev Rashid R. 1,4 , Uvarov Mikhail N. 5 , Mostovich Evgeny.A. 2,3 , Postnikov Pavel S. 1
Организации
1 (Данные Web of science) Tomsk Polytech Univ, Tomsk 634050, Russia
2 (Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3 (Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
4 (Данные Web of science) Tomsk State Univ, Tomsk 634050, Russia
5 (Данные Web of science) Russian Acad Sci, VV Voevodsky Inst Chem Kinet & Combust, Siberian Branch, Novosibirsk 630090, Russia

Реферат: A general and effective method for the synthesis of 3-phenylveradzyl radicals bearing a variety of iodophenyl substituents has been developed. The synthesized radicals have been characterized by ESR, UV/Vis spectroscopy, and cyclic voltammetry. Structures of biphenyl-substituted radicals have been solved by X-ray crystal structure analysis. The synthesized iodoverdazyls are applicable in the Sonogashira coupling reaction for the preparation of a wide range of ethynyl derivatives. Both N-2 and C-6 substituents were functionalized through Sonogashira coupling.
Библиографическая ссылка: Petunin P.V. , Martynko E.A. , Trusova M.E. , Kazantsev M.S. , Rybalova T.V. , Valiev R.R. , Uvarov M.N. , Mostovich E.A. , Postnikov P.S.
Verdazyl Radical Building Blocks: Synthesis, Structure, and Sonogashira Cross-Coupling Reactions
European Journal of Organic Chemistry. 2018. V.2018. N34. P.4802-4811. DOI: 10.1002/ejoc.201701783 WOS Scopus РИНЦ
Даты:
Опубликована online: 30 мар. 2018 г.
Опубликована в печати: 16 сент. 2018 г.
Идентификаторы:
Web of science WOS:000444540900019
Scopus 2-s2.0-85053324309
РИНЦ 35723140
OpenAlex W2792975557
Альметрики: