Hexa(isothiocyanato)chromates(III) of Some Yttrium Group Lanthanide(III) and Europium Complexes with Nicotinic Acid: Synthesis and Crystal Structures

Hexa(isothiocyanato)chromates(III) of Some Yttrium Group Lanthanide(III) and Europium Complexes with Nicotinic Acid: Synthesis and Crystal Structures Научная публикация

Журнал

Russian Journal of Inorganic Chemistry
ISSN: 0036-0236

Вых. Данные

Год: 2018, Том: 63, Номер: 5, Страницы: 626-630 Страниц : 5 DOI: 10.1134/S003602361805011X

Авторы

Cherkasova E.V. ¹ , Pervukhina N.V. ² , Kuratieva N.V. ^2,4 , Bagryanskaya I.Yu. ^3,4 , Cherkasova T.G. ¹

Организации

1	(Данные Web of science) TF Gorbachev Kuzbass State Tech Univ, Kemerovo 650000, Russia
2	(Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
4	(Данные Web of science) Novosibirsk Natl Res State Univ, Novosibirsk 630090, Russia

Double ionic complexes [M(C5H5NCOO)(3)(H2O)(2)][Cr(NCS)(6)] center dot nH(2)O, where M = Eu (I), n = 1.15; Dy (II), Er (III), n = 1.5; M = Yb (IV), n = 2, have been synthesized by the reaction between M(NO3)(3), M = Eu, Dy, Er, Yb, K-3[Cr(NCS)(6)], and nicotinic acid (C5H5NCOO) in an aqueous solution and studied by chemical analysis, IR spectroscopy, and X-ray diffraction. Crystals of complexes I-IV are monoclinic, space group P2(1)/n, Z = 4; a = 9.5358(2) , b = 25.4871(5) , c = 15.4303(4) , beta = 105.513(1)A degrees, V = 3613.6(1) (3), rho(calcd) = 1.799 g/cm(3) for I, a = 9.5901(5) , b = 25.8599(15) , c = 15.6316(9) , beta = 106.829(2)A degrees, V = 3710.6(4) (3), rho(calcd) = 1.782 g/cm(3) for II, a = 9.5640(3) , b = 25.8936(11) , c = 15.6498(7) , beta = 106.895(2)A degrees, V = 3708.3(3) (3), rho(calcd) = 1.791 g/cm(3) for III, and a = 9.5049(2) , b = 25.6378(4) , c = 15.5120(3) , beta = 106.934(1)A degrees, V = 3616.1(1) (3), rho(calcd) = 1.864 g/cm(3) for IV.

Cherkasova E.V. , Pervukhina N.V. , Kuratieva N.V. , Bagryanskaya I.Y. , Cherkasova T.G.
Hexa(isothiocyanato)chromates(III) of Some Yttrium Group Lanthanide(III) and Europium Complexes with Nicotinic Acid: Synthesis and Crystal Structures
Russian Journal of Inorganic Chemistry. 2018. V.63. N5. P.626-630. DOI: 10.1134/S003602361805011X WOS Scopus РИНЦ

Черкасова Е.В. , Первухина Н.В. , Куратьева Н.В. , Багрянская И.Ю. , Черкасова Т.Г.
Синтез и кристаллические структуры гекса(изотиоцианато)хроматов(iii) комплексов некоторых лантаноидов(iii) иттриевой группы и европия с никотиновой кислотой
Журнал неорганической химии. 2018. Т.63. №5. С.596-600. РИНЦ

Опубликована в печати:	1 мая 2018 г.
Опубликована online:	7 июн. 2018 г.

Web of science	WOS:000434718000010
Scopus	2-s2.0-85048301393
РИНЦ	35759357
OpenAlex	W2806281120