Isomerization as a tool to design volatile heterometallic complexes with methoxy-substituted -diketonates

Isomerization as a tool to design volatile heterometallic complexes with methoxy-substituted -diketonates Научная публикация

Журнал

Journal of Coordination Chemistry
ISSN: 0095-8972 , E-ISSN: 1029-0389

Вых. Данные

Год: 2018, Том: 71, Номер: 14, Страницы: 2194-2208 Страниц : 15 DOI: 10.1080/00958972.2018.1479746

Ключевые слова

Volatile heterometallic complexes; fluorinated metal -diketonates; lead(II) diketonates; copper(II) diketonates; crystal structure; thermal properties; geometric isomerization; MOCVD precursors

Авторы

Krisyuk Vladislav V. ¹ , Kyzy Samara Urkasym ¹ , Rybalova Tatyana V. ^2,3 , Baidina Iraida A. ¹ , Korolkov Ilya V. ^1,3 , Chizhov Dmitry L. ⁴ , Bazhin Denis N. ⁴ , Kudyakova Yulia S. ⁴

Организации

1	(Данные Web of science) RAS, SB, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
2	(Данные Web of science) RAS, SB, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk, Russia
3	(Данные Web of science) Novosibirsk State Univ, Dept Nat Sci, Novosibirsk, Russia
4	(Данные Web of science) RAS, UB, Postovsky Inst Organ Synth, Ekaterinburg, Russia

A series of new heterometallic compounds have been obtained by the co-crystallization of Cu(II) methoxy-substituted -diketonates and Pb(II) hexafluoroacetylacetonate (hfac) from organic solvents. Their crystal structures were established by X-ray analysis. It is shown that the formation of heterometallic compounds proceeds with geometrical isomerization of the initial copper complexes, which can be controlled by varying terminal substituents in the ligand. Due to the ability of copper complexes to isomerize, the structure of the resulting heterocomplexes can be flexibly and purposefully changed from polymeric to discrete molecular forms. The study of the thermal properties shows that all the reported compounds are volatile and can be re-sublimed in a vacuum, with their composition and structure being retained. [GRAPHICS] .

Krisyuk V.V. , Kyzy S.U. , Rybalova T.V. , Baidina I.A. , Korolkov I.V. , Chizhov D.L. , Bazhin D.N. , Kudyakova Y.S.
Isomerization as a tool to design volatile heterometallic complexes with methoxy-substituted -diketonates
Journal of Coordination Chemistry. 2018. V.71. N14. P.2194-2208. DOI: 10.1080/00958972.2018.1479746 WOS Scopus РИНЦ

Опубликована online:	8 июн. 2018 г.
Опубликована в печати:	18 июл. 2018 г.

Web of science	WOS:000451257000008
Scopus	2-s2.0-85048174744
РИНЦ	38610670
OpenAlex	W2804925368