Formation of stable 1,2,3-benzodithiazolyl radicals by thermolysis of 1,3,2,4-benzodithiadiazines

Formation of stable 1,2,3-benzodithiazolyl radicals by thermolysis of 1,3,2,4-benzodithiadiazines Научная публикация

Журнал

Mendeleev Communications
ISSN: 0959-9436

Вых. Данные

Год: 2000, Том: 10, Номер: 1, Страницы: 5-7 Страниц : 3 DOI: 10.1070/mc2000v010n01abeh001198

Авторы

Bagryansky V.A. ¹ , Vlasyuk I.V. ² , Gatilov Y.V. ³ , Makarov A.Yu. ³ , Molin Y.N. ¹ , Shcherbukhin V.V. ⁴ , Zibarev A.V. ³

Организации

1	Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
2	Department of Natural Sciences, Novosibirsk State University, 630090 Novosibirsk, Russian Federation
3	N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences 630090 Novosibirsk, Russian Federation
4	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913 Moscow, Russian Federation

Mild thermolysis (at 110-150 °C) of 1,3,2,4-benzodithiadiazine 1 and its derivatives 2-6 in hydrocarbon solvents quantitatively yielded stable 1,2,3-benzodithiazolyl π-radicals via a first-order reaction (Ea = 76.2 kJ mol-1, k0 = 4.34×105 s-1 for 1).

Bagryansky V.A. , Vlasyuk I.V. , Gatilov Y.V. , Makarov A.Y. , Molin Y.N. , Shcherbukhin V.V. , Zibarev A.V.
Formation of stable 1,2,3-benzodithiazolyl radicals by thermolysis of 1,3,2,4-benzodithiadiazines
Mendeleev Communications. 2000. V.10. N1. P.5-7. DOI: 10.1070/mc2000v010n01abeh001198 WOS Scopus РИНЦ

Опубликована в печати:

1 янв. 2000 г.

Web of science	WOS:000085384000003
Scopus	2-s2.0-0038957503
РИНЦ	13335692
OpenAlex	W1967698021