Transformations of 2-aminopyrimidines and their N-oxides under diazotization conditions

Transformations of 2-aminopyrimidines and their N-oxides under diazotization conditions Научная публикация

Журнал

Chemistry of Heterocyclic Compounds
ISSN: 0009-3122 , E-ISSN: 1573-8353

Вых. Данные

Год: 1983, Том: 19, Номер: 1, Страницы: 91-95 Страниц : 5 DOI: 10.1007/BF00512824

Авторы

Sedova V.F. ¹ , Mustafina T.Yu. ¹ , Krivopalov V.P. ¹ , Mamaev V.P. ¹

Организации

1	(Scopus) Novosibirsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk, 630090, Russian Federation

The diazotization of 2-aminopyrimidines and their N-oxides in solutions with various acidities was studied. It is shown that the amino group in pyrimidine N-oxides is not diazotized in strongly acidic media and that bromination in the 5 position of the pyrimidine ring is observed in concentrated hydrobromic acid. When the reaction was carried out in moderately acidic media, it was possible to synthesize the difficult-to-obtain 2-halopyrimidine N-oxides. © 1983 Plenum Publishing Corporation.

Sedova V.F. , Mustafina T.Y. , Krivopalov V.P. , Mamaev V.P.
Transformations of 2-aminopyrimidines and their N-oxides under diazotization conditions
Chemistry of Heterocyclic Compounds. 1983. V.19. N1. P.91-95. DOI: 10.1007/BF00512824 Scopus РИНЦ

Sedova V.F. , Mustafina T.Y. , Krivopalov V.P. , Mamayev V.P.
TRANSFORMATIONS OF 2-AMINOPYRIMIDINES AND THEIR N-OXIDES IN DIAZOTIZATION REACTION
Химия гетероциклических соединений/Khimiya Geterotsiklicheskikh Soedinenii. 1983. N1. P.102-106. WOS

Опубликована в печати:

1 янв. 1983 г.

Scopus	2-s2.0-34250144835
РИНЦ	30901935
OpenAlex	W3170181503