Second-order nonlinear optical properties of composite material of an azo-chromophore with a tricyanodiphenyl acceptor in a poly(styrene-co-methyl methacrylate) matrix

Second-order nonlinear optical properties of composite material of an azo-chromophore with a tricyanodiphenyl acceptor in a poly(styrene-co-methyl methacrylate) matrix Научная публикация

Журнал

Optical Materials
ISSN: 0925-3467 , E-ISSN: 1873-1252

Вых. Данные

Год: 2017, Том: 69, Страницы: 67-72 Страниц : 6 DOI: 10.1016/j.optmat.2017.04.008

Ключевые слова

Second-order nonlinear optical properties; Azo-chromophore; Tricyanodiphenyl acceptor; Polymer-chromophore film

Авторы

Shelkovnikov Vladimir ^1,2 , Selivanova Galina ¹ , Lyubas Gleb ¹ , Korotaev Sergey ¹ , Shundrina Inna ¹ , Tretyakov Evgeny ¹ , Zueva Ekaterina ^3,4 , Plekhanov Alexander ⁵ , Mikerin Sergey ⁵ , Simanchuk Andrey ⁵

Организации

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Inst Organ Chem, Pr Lavrentjeva 9, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Tech Univ, Pr K Marksa 20, Novosibirsk 630073, Russia
3	(Данные Web of science) Kazan Natl Res Technol Univ, 68 K Marx Str, Kazan 420015, Russia
4	(Данные Web of science) Kazan Fed Univ, 18 Kremlevskaya Str, Kazan 420008, Russia
5	(Данные Web of science) Russian Acad Sci, Siberian Branch, Inst Automat & Electrometry, Pr Koptyuga 1, Novosibirsk 630090, Russia

The composite material of new synthesized 4-((4-(N,N-n-dibutylamino) phenyl)diazenyl)-biphenyl-2,3,4-tricarbonitrile (GAS dye) in commercial poly(styrene-co-methyl methacrylate) (PSMMA) was prepared, poled and its nonlinear optical properties compared with DR1 dye were studied. High thermal stability of the composite material was revealed, and the maximal concentration of the chromophore was found to reach similar to 20 wt%. The dipole moment, polarizability tensor, and first hyperpolarizability tensor of the investigated dyes were calculated by within the framework of the coupled perturbed density functional theory. A nanosecond second-harmonic generation Maker fringes technique was used which is capable of providing the magnitude of the second-order nonlinearity of optical materials at a wavelength of 1064 nm. For the tested GAS PSMMA composite material, maximal coefficient d(33) was found to be 50 pm/V. The nonlinear optical response, which was achieved here, shows possible usefulness of the GAS dye as a component for molecular design of nonlinear-optical materials with advanced characteristics. (C) 2017 Elsevier B.V. All rights reserved.

Shelkovnikov V. , Selivanova G. , Lyubas G. , Korotaev S. , Shundrina I. , Tretyakov E. , Zueva E. , Plekhanov A. , Mikerin S. , Simanchuk A.
Second-order nonlinear optical properties of composite material of an azo-chromophore with a tricyanodiphenyl acceptor in a poly(styrene-co-methyl methacrylate) matrix
Optical Materials. 2017. V.69. P.67-72. DOI: 10.1016/j.optmat.2017.04.008 WOS Scopus

Опубликована в печати:

1 июл. 2017 г.

Web of science	WOS:000404305200009
Scopus	2-s2.0-85017462031
OpenAlex	W2605870597