Chapter 2: Kinetic aspects of nitroxide mediated polymerization

Chapter 2: Kinetic aspects of nitroxide mediated polymerization Научная публикация

Журнал

RSC Polymer Chemistry Series
ISSN: 2044-0790 , E-ISSN: 2044-0804

Вых. Данные

Год: 2016, Том: 2016-January, Номер: 19, Страницы: 45-113 Страниц : 69 DOI: 10.1039/9781782622635-00045

Авторы

Bagryanskaya Elena G. ^1,2 , Marque Sylvain R.A. ³

Организации

1	(Scopus) N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RAS, Pr. Lavrentjeva 9, 630090 Novosibirsk, Russia, Russian Federation
2	(Scopus) Novosibirsk State University, Pirogova 2, Novosibirsk, 630090, Russian Federation
3	(Scopus) Aix Marseille Universit?, CNRS, ICR UMR 7273, Marseille Cedex 20, 13397, France

The peculiarities of key reactions in nitroxide-mediated polymerization and the main factors that determine their rate constants are discussed. The process and kinetics of nitroxide-mediated polymerization is determined by the rate constants of: (i) the decomposition of alkoxyamines and macroalkoxyamines, (ii) the recombination of nitroxides and alkyl radicals and (iii) the side reactions. The methods and techniques for the determination of these rate constants are also discussed.

Bagryanskaya E.G. , Marque S.R.A.
Chapter 2: Kinetic aspects of nitroxide mediated polymerization
RSC Polymer Chemistry Series. 2016. V.2016-January. N19. P.45-113. DOI: 10.1039/9781782622635-00045 WOS Scopus РИНЦ

Web of science	WOS:000387089000003
Scopus	2-s2.0-84951742880
РИНЦ	26927621
OpenAlex	W2345866240