Synthesis of Fluorinated Octahydro-2H-Chromenes in the Presence of the BF3·Et2O–H2O Catalytic System

Synthesis of Fluorinated Octahydro-2H-Chromenes in the Presence of the BF3·Et2O–H2O Catalytic System Научная публикация

Журнал

Chemistry of Heterocyclic Compounds
ISSN: 0009-3122 , E-ISSN: 1573-8353

Вых. Данные

Год: 2020, Том: 56, Номер: 7, Страницы: 867-874 Страниц : 8 DOI: 10.1007/s10593-020-02743-z

Ключевые слова

acid catalysts; boron trifluoride etherate; chromene; isopulegol; monoterpenes; organofluorine compounds; Prins reaction

Авторы

I?ina I.V. ¹ , Patrusheva O.S. ¹ , Korchagina D.V. ¹ , Volcho K.P. ^1,2 , Salakhutdinov N.F. ^1,2

Организации

1	(Scopus) N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 Akademika Lavrentieva Ave, Novosibirsk, 630090, Russian Federation
2	(Scopus) Novosibirsk State University, 2 Pirogova St, Novosibirsk, 630090, Russian Federation

[Figure not available: see fulltext.] The synthesis of fluorinated octahydro-2H-chromene was carried out using the Prins reaction between the monoterpenoid (–)-isopulegol and carbonyl compounds in the presence of the BF3·Et2O–H2O system, which acts as both an acid catalyst and a fluorine source. The use of the readily available and easy-to-use BF3·Et2O reagent makes this method of obtaining fluorine derivatives simple and practical. © 2020, Springer Science+Business Media, LLC, part of Springer Nature.

I?ina I.V. , Patrusheva O.S. , Korchagina D.V. , Volcho K.P. , Salakhutdinov N.F.
Synthesis of Fluorinated Octahydro-2H-Chromenes in the Presence of the BF3·Et2O–H2O Catalytic System
Chemistry of Heterocyclic Compounds. 2020. V.56. N7. P.867-874. DOI: 10.1007/s10593-020-02743-z WOS Scopus РИНЦ

Опубликована в печати:	1 июл. 2020 г.
Опубликована online:	22 авг. 2020 г.

Web of science	WOS:000561722700004
Scopus	2-s2.0-85089725054
РИНЦ	45369239
OpenAlex	W3080283772