Luminescent Complexes of Zn(II) and Cd(II) with Chiral Ligands Containing 1,10-Phenanthroline and Natural Monoterpenoids (+)-3-Carene or (+)-Limonene Fragments

Luminescent Complexes of Zn(II) and Cd(II) with Chiral Ligands Containing 1,10-Phenanthroline and Natural Monoterpenoids (+)-3-Carene or (+)-Limonene Fragments Научная публикация

Журнал

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Вых. Данные

Год: 2019, Том: 89, Номер: 1, Страницы: 87-95 Страниц : 9 DOI: 10.1134/S107036321901016X

Ключевые слова

terpenes; complexes; zinc; cadmium; luminescence

Авторы

Kokina T.E. ^1,2 , Ustimenko Yu.P. ³ , Rakhmanova M.I. ¹ , Sheludyakova L.A. ^1,2 , Agafontsev A.M. ³ , Plyusnin P.E. ^1,2 , Tkachev A.V. ^2,3 , Larionov S.V. ^1,2

Организации

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, AV Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
2	(Данные Web of science) Novosibirsk Natl Res State Univ, Novosibirsk, Russia
3	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk, Russia

New chiral 1,10-phenanthroline-derived ligands containing fragments of (+)-3-carene (L-1) and (+)-limonene (L2) natural monoterpenoids and their complexes Zn(L-1,L-2)Cl(2)1.5H(2)O, Cd(L-1,L-2)Cl(2)nH(2)O, Zn(L-1)Br2H2O, and Cd(L1)Br22H2O were synthesized. According to NMR and IR spectroscopy data, a conclusion was made about the polynuclear structure of the compounds obtained. Luminescent properties of the compounds obtained were investigated. Lifetimes of the excited states and luminescence quantum yields (phi(f)) were determined. For free ligands, blue fluorescence was observed. In the case of Zn(II) and Cd(II) complexes, luminescence appeared in the green region of the spectrum.

Kokina T.E. , Ustimenko Y.P. , Rakhmanova M.I. , Sheludyakova L.A. , Agafontsev A.M. , Plyusnin P.E. , Tkachev A.V. , Larionov S.V.
Luminescent Complexes of Zn(II) and Cd(II) with Chiral Ligands Containing 1,10-Phenanthroline and Natural Monoterpenoids (+)-3-Carene or (+)-Limonene Fragments
Russian Journal of General Chemistry. 2019. V.89. N1. P.87-95. DOI: 10.1134/S107036321901016X WOS Scopus РИНЦ

Кокина Т.Е. , Устименко Ю.П. , Рахманова М.И. , Шелудякова Л.А. , Агафонцев А.М. , Плюснин П.Е. , Ткачев А.В. , Ларионов С.В.
Люминесцирующие комплексы Zn(II) и Cd(I) c хиральными лигандами, содержащими фрагменты 1,10-фенантролина и природных монотерпеноидов (+)-3-карена или (+)-лимонена
Журнал общей химии (RUSS J GEN CHEM+). 2019. Т.89. №1. С.100-109. DOI: 10.1134/S0044460X19010165 РИНЦ

Опубликована в печати:	1 янв. 2019 г.
Опубликована online:	3 апр. 2019 г.

Web of science	WOS:000463631500016
Scopus	2-s2.0-85064008854
РИНЦ	38672754
OpenAlex	W2927276514