Реферат: Poly(ethylene succinate) and poly(butylene succinate) are synthetic biodegradable polymers, and much attention is paid to study the properties of pure polymers and the polymers modified by different comonomers and filling materials. The literature data on the physical properties of these polymers vary widely depending on their method of preparation and subsequent modifications. Most of the studies deal with low- and moderate-molecular-weight polymers or commercial grade polymers, modified by different comonomers and chain-extension agents. The data on pure high-molecular-weight polymers are scarce. In this work, we have prepared high-molecular-weight (MW range of (1.4-1.8) x 10(5)) poly(ethylene succinate) and poly(butylene succinate) by direct polycondensation at 200A degrees C in a nitrogen flow without chain-extension agents. We have further studied the properties of pure polymers and examined the effect of different fillers (carbon nanotubes, SiO2, AerosilA (R)) on the mechanical and physical properties of these polymers. Because of high-molecular-weight, the polymers possess increased tensile and storage moduli and thermostability. Even very low filler contents (up to 1 wt %) have a pronounced influence on the polymer properties: the polymer tensile and the storage modulus increases, the elongation at break decreases, and the thermal stability of the polymers decreases slightly. The effects of fillers are less pronounced compared with those for low- and moderate-molecular-weight polymers. When mixed together, poly(ethylene succinate) and poly(butylene succinate) crystallize independently from each other as evident from the mechanical and thermal analysis data.

Библиографическая ссылка: Potapov A.G. , Shundrina I.K.
The influence of different fillers on mechanical and physical properties of high-molecular-weight biodegradable aliphatic polyesters
Polymer Science - Series A. 2016. V.58. N4. P.585-592. DOI: 10.1134/S0965545X1604012X WOS Scopus РИНЦ

Даты:

Опубликована в печати:	1 июл. 2016 г.
Опубликована online:	22 июл. 2016 г.

Идентификаторы:

Web of science	WOS:000381087700011
Scopus	2-s2.0-84979258351
РИНЦ	27094090
OpenAlex	W2499661770

Альметрики: