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Preparation of Diversely Substituted Triarylmethyl Radicals by the Quenching of Tris(2,3,5,6-tetrathiaaryl)methyl Cations with C-, N-, P-, and S-Nucleophiles Full article

Journal European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690
Output data Year: 2014, Volume: 2014, Number: 2, Pages: 371-380 Pages count : DOI: 10.1002/ejoc.201301161
Tags Carbocations; Radicals; Electron transfer; Nucleophilic addition; Reaction mechanisms
Authors Tormyshev Victor M. 1,2 , Rogozhnikova Olga Yu. 1 , Bowman Michael K. 3 , Trukhin Dmitry V. 1 , Troitskaya Tatiana I. 1 , Vasiliev Vladimir G. 1 , Shundrin Leonid A. 1 , Halpern Howard J. 4
Affiliations
1 (Данные Web of science) Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
2 (Данные Web of science) Novosibirsk State Univ, Natl Res Univ, Dept Nat Sci, Novosibirsk 630090, Russia
3 (Данные Web of science) Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA
4 (Данные Web of science) Univ Chicago, Dept Radiat & Cellular Oncol, Ctr EPR Imaging Vivo Physiol, Chicago, IL 60637 USA

Abstract: C-, N-, P-, and S-nucleophiles reacted with symmetrical tris(2,3,5,6-tetrathiaaryl)methyl cations, generated from the corresponding triarylmethanols by strong acids, to give a variety of asymmetrical monosubstituted persistent triarylmethyl (TAM) radicals as the major products. The only by-products were symmetrical TAMs.
Cite: Tormyshev V.M. , Rogozhnikova O.Y. , Bowman M.K. , Trukhin D.V. , Troitskaya T.I. , Vasiliev V.G. , Shundrin L.A. , Halpern H.J.
Preparation of Diversely Substituted Triarylmethyl Radicals by the Quenching of Tris(2,3,5,6-tetrathiaaryl)methyl Cations with C-, N-, P-, and S-Nucleophiles
European Journal of Organic Chemistry. 2014. V.2014. N2. P.371-380. DOI: 10.1002/ejoc.201301161 WOS Scopus РИНЦ
Files: Full text from publisher
Dates:
Published online: Nov 6, 2013
Published print: Jan 1, 2014
Identifiers:
Web of science WOS:000336266400012
Scopus 2-s2.0-84891873467
Elibrary 21862759
OpenAlex W1755783564
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