Preparation of Diversely Substituted Triarylmethyl Radicals by the Quenching of Tris(2,3,5,6-tetrathiaaryl)methyl Cations with C-, N-, P-, and S-Nucleophiles

Preparation of Diversely Substituted Triarylmethyl Radicals by the Quenching of Tris(2,3,5,6-tetrathiaaryl)methyl Cations with C-, N-, P-, and S-Nucleophiles Научная публикация

Журнал

European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690

Вых. Данные

Год: 2014, Том: 2014, Номер: 2, Страницы: 371-380 Страниц : DOI: 10.1002/ejoc.201301161

Ключевые слова

Carbocations; Radicals; Electron transfer; Nucleophilic addition; Reaction mechanisms

Авторы

Tormyshev Victor M. ^1,2 , Rogozhnikova Olga Yu. ¹ , Bowman Michael K. ³ , Trukhin Dmitry V. ¹ , Troitskaya Tatiana I. ¹ , Vasiliev Vladimir G. ¹ , Shundrin Leonid A. ¹ , Halpern Howard J. ⁴

Организации

1	(Данные Web of science) Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Natl Res Univ, Dept Nat Sci, Novosibirsk 630090, Russia
3	(Данные Web of science) Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA
4	(Данные Web of science) Univ Chicago, Dept Radiat & Cellular Oncol, Ctr EPR Imaging Vivo Physiol, Chicago, IL 60637 USA

C-, N-, P-, and S-nucleophiles reacted with symmetrical tris(2,3,5,6-tetrathiaaryl)methyl cations, generated from the corresponding triarylmethanols by strong acids, to give a variety of asymmetrical monosubstituted persistent triarylmethyl (TAM) radicals as the major products. The only by-products were symmetrical TAMs.

Tormyshev V.M. , Rogozhnikova O.Y. , Bowman M.K. , Trukhin D.V. , Troitskaya T.I. , Vasiliev V.G. , Shundrin L.A. , Halpern H.J.
Preparation of Diversely Substituted Triarylmethyl Radicals by the Quenching of Tris(2,3,5,6-tetrathiaaryl)methyl Cations with C-, N-, P-, and S-Nucleophiles

European Journal of Organic Chemistry. 2014. V.2014. N2. P.371-380. DOI: 10.1002/ejoc.201301161 WOS Scopus РИНЦ

Полный текст от издателя

Опубликована online:	6 нояб. 2013 г.
Опубликована в печати:	1 янв. 2014 г.

Web of science	WOS:000336266400012
Scopus	2-s2.0-84891873467
РИНЦ	21862759
OpenAlex	W1755783564