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Pentafluorophenyl vinyl ketone: Synthesis, radical polymerization, copolymerization, and polymer degradation under ultra-violet irradiation Full article

Journal Journal of Polymer Science
ISSN: 2642-4150
Output data Year: 2023, Volume: 61, Number: 20, Pages: 2462-2474 Pages count : 13 DOI: 10.1002/pol.20230185
Tags copolymerization, fluoropolymers, photodegradation, poly(vinyl ketone)s
Authors Kaletina Polina M. 1,2 , Vinogradov Andrey S. 1 , Shaparenko Nikita O. 3 , Parkhomenko Dmitriy A. 1 , Shundrina Inna K. 1 , Mezhenkova Tatyana V. 1 , Bagryanskaya Elena G. 1
Affiliations
1 N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of Siberian Branch of Russian Academy of Sciences
2 Novosibirsk State University
3 Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the RAS

Abstract: In this study, we report the synthesis of a new fluorinated vinyl monomer, that is, pentafluorophenyl vinyl ketone [1-(pentafluorophenyl)prop-2-en-1-one], its radical polymerization and copolymerization with styrene, methyl vinyl ketone, or phenyl vinyl ketone. The obtained homo- and co-polymers were subjected to thermal analysis, contact angle measurement, and an assay of resistance to UV irradiation. The results showed that the poly(pentafluorophenyl vinyl ketone) has a slightly greater contact angle and a lower temperature of the maximum decomposition rate when compared to the nonfluorinated analog: poly(phenyl vinyl ketone).
Cite: Kaletina P.M. , Vinogradov A.S. , Shaparenko N.O. , Parkhomenko D.A. , Shundrina I.K. , Mezhenkova T.V. , Bagryanskaya E.G.
Pentafluorophenyl vinyl ketone: Synthesis, radical polymerization, copolymerization, and polymer degradation under ultra-violet irradiation
Journal of Polymer Science. 2023. V.61. N20. P.2462-2474. DOI: 10.1002/pol.20230185 WOS Scopus РИНЦ
Dates:
Submitted: Mar 23, 2023
Accepted: Jul 3, 2023
Published online: Jul 19, 2023
Published print: Oct 15, 2023
Identifiers:
Web of science WOS:001028698500001
Scopus 2-s2.0-85165367121
Elibrary 65196932
OpenAlex W4384824088
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