Pentafluorophenyl vinyl ketone: Synthesis, radical polymerization, copolymerization, and polymer degradation under ultra-violet irradiation

Pentafluorophenyl vinyl ketone: Synthesis, radical polymerization, copolymerization, and polymer degradation under ultra-violet irradiation Научная публикация

Журнал

Journal of Polymer Science
ISSN: 2642-4150

Вых. Данные

Год: 2023, Том: 61, Номер: 20, Страницы: 2462-2474 Страниц : 13 DOI: 10.1002/pol.20230185

Ключевые слова

copolymerization, fluoropolymers, photodegradation, poly(vinyl ketone)s

Авторы

Kaletina Polina M. ^1,2 , Vinogradov Andrey S. ¹ , Shaparenko Nikita O. ³ , Parkhomenko Dmitriy A. ¹ , Shundrina Inna K. ¹ , Mezhenkova Tatyana V. ¹ , Bagryanskaya Elena G. ¹

Организации

1	Новосибирский институт органической химии им. Н.Н. Ворожцова СО РАН
2	Новосибирский национальный исследовательский государственный университет
3	Институт неорганической химии им. А.В. Николаева СО РАН

In this study, we report the synthesis of a new fluorinated vinyl monomer, that is, pentafluorophenyl vinyl ketone [1-(pentafluorophenyl)prop-2-en-1-one], its radical polymerization and copolymerization with styrene, methyl vinyl ketone, or phenyl vinyl ketone. The obtained homo- and co-polymers were subjected to thermal analysis, contact angle measurement, and an assay of resistance to UV irradiation. The results showed that the poly(pentafluorophenyl vinyl ketone) has a slightly greater contact angle and a lower temperature of the maximum decomposition rate when compared to the nonfluorinated analog: poly(phenyl vinyl ketone).

Kaletina P.M. , Vinogradov A.S. , Shaparenko N.O. , Parkhomenko D.A. , Shundrina I.K. , Mezhenkova T.V. , Bagryanskaya E.G.
Pentafluorophenyl vinyl ketone: Synthesis, radical polymerization, copolymerization, and polymer degradation under ultra-violet irradiation
Journal of Polymer Science. 2023. V.61. N20. P.2462-2474. DOI: 10.1002/pol.20230185 WOS Scopus РИНЦ

Поступила в редакцию:	23 мар. 2023 г.
Принята к публикации:	3 июл. 2023 г.
Опубликована online:	19 июл. 2023 г.
Опубликована в печати:	15 окт. 2023 г.

Web of science	WOS:001028698500001
Scopus	2-s2.0-85165367121
РИНЦ	65196932
OpenAlex	W4384824088