Synthesis of 5,5-Disubstituted N-Methyl-1,3-oxazinanes Containing Monoterpene Fragments Full article
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Doklady Chemistry
ISSN: 0012-5008 |
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Output data | Year: 2023, Volume: 512 part 2, Pages: 281-287 Pages count : 7 DOI: 10.1134/S001250082360058X | ||
Tags | oxazine, tetrahydro-1,3-oxazine, oxazinane, aminopropanol, propanolamine, pinene, Knoevenagel condensation, alkylation of cyanoacetic ester, ethyl cyanoacetate | ||
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Abstract:
A new method has been developed for the synthesis of 5,5-disubstituted N-methyl-1,3-oxazinanes as a mixture of diastereomers at the 5-position containing monoterpene and branched alkyl substituents in the 5-position. 1,3-Oxazinanes were obtained for the first time by reacting 2,2-substituted 3-aminopropan-1-ols with formaldehyde and sodium borohydride in one stage.
Cite:
Nechepurenko I.V.
, Volcho K.P.
, Salakhutdinov N.F.
Synthesis of 5,5-Disubstituted N-Methyl-1,3-oxazinanes Containing Monoterpene Fragments
Doklady Chemistry. 2023. V.512 part 2. P.281-287. DOI: 10.1134/S001250082360058X WOS РИНЦ
Synthesis of 5,5-Disubstituted N-Methyl-1,3-oxazinanes Containing Monoterpene Fragments
Doklady Chemistry. 2023. V.512 part 2. P.281-287. DOI: 10.1134/S001250082360058X WOS РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Нечепуренко И.В.
, Волчо К.П.
, Салахутдинов Н.Ф.
СИНТЕЗ 5,5-ДИЗАМЕЩЕННЫХ N-МЕТИЛ-1,3-ОКСАЗИНАНОВ, СОДЕРЖАЩИХ МОНОТЕРПЕНОВЫЕ ФРАГМЕНТЫ
Доклады Российской академии наук. Химия, науки о материалах.. 2023. Т.512. С.75-82. DOI: 10.31857/S2686953522600283 РИНЦ
СИНТЕЗ 5,5-ДИЗАМЕЩЕННЫХ N-МЕТИЛ-1,3-ОКСАЗИНАНОВ, СОДЕРЖАЩИХ МОНОТЕРПЕНОВЫЕ ФРАГМЕНТЫ
Доклады Российской академии наук. Химия, науки о материалах.. 2023. Т.512. С.75-82. DOI: 10.31857/S2686953522600283 РИНЦ
Dates:
Submitted: | Jun 9, 2022 |
Accepted: | Nov 21, 2022 |
Identifiers:
Web of science | WOS:001130184300001 |
Elibrary | 65019761 |
OpenAlex | W4390191029 |