Transformations of several monoterpenoids in the presence of aldehydes in supercritical solvents

Transformations of several monoterpenoids in the presence of aldehydes in supercritical solvents Full article

Journal

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Output data

Year: 2013, Volume: 87, Number: 3, Pages: 382-387 Pages count : DOI: 10.1134/S0036024413030023

Tags

supercritical solvent; terpenoids; verbenol epoxide; isopulegol; aldehydes; alumina

Authors

Anikeev V. I. ¹ , Sivcev V. P. ² , Il'ina I. V. ³ , Korchagina D. V. ³ , Statsenko O. B. ³ , Volcho K. P. ³ , Salakhutdinov N. F. ³

Affiliations

1	(Данные Web of science) Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk, Russia

The reactivity of verbenol epoxide and isopulegol in supercritical solvents in the presence of aromatic aldehydes was studied using a flow type reactor and a heterogeneous catalyst (Al2O3) or no catalyst. The intramolecular transformations or interactions of reagents with the solvent prevailed in all cases; the yield of the products of intermolecular reactions of terpenoids with aldehydes was up to 1%. The aldehydes did not interact with verbenol epoxide but produced a considerable effect on the distribution of its isomerization products.

Anikeev V.I. , Sivcev V.P. , Il'ina I.V. , Korchagina D.V. , Statsenko O.B. , Volcho K.P. , Salakhutdinov N.F.
Transformations of several monoterpenoids in the presence of aldehydes in supercritical solvents
Russian Journal of Physical Chemistry A. 2013. V.87. N3. P.382-387. DOI: 10.1134/S0036024413030023 WOS Scopus РИНЦ

Published online:	Feb 3, 2013
Published print:	Mar 1, 2013

Web of science	WOS:000314407800008
Scopus	2-s2.0-84879657264
Elibrary	20437382
OpenAlex	W2074440730