Transformations of several monoterpenoids in the presence of aldehydes in supercritical solvents

Transformations of several monoterpenoids in the presence of aldehydes in supercritical solvents Научная публикация

Журнал

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Вых. Данные

Год: 2013, Том: 87, Номер: 3, Страницы: 382-387 Страниц : DOI: 10.1134/S0036024413030023

Ключевые слова

supercritical solvent; terpenoids; verbenol epoxide; isopulegol; aldehydes; alumina

Авторы

Anikeev V. I. ¹ , Sivcev V. P. ² , Il'ina I. V. ³ , Korchagina D. V. ³ , Statsenko O. B. ³ , Volcho K. P. ³ , Salakhutdinov N. F. ³

Организации

1	(Данные Web of science) Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk, Russia

The reactivity of verbenol epoxide and isopulegol in supercritical solvents in the presence of aromatic aldehydes was studied using a flow type reactor and a heterogeneous catalyst (Al2O3) or no catalyst. The intramolecular transformations or interactions of reagents with the solvent prevailed in all cases; the yield of the products of intermolecular reactions of terpenoids with aldehydes was up to 1%. The aldehydes did not interact with verbenol epoxide but produced a considerable effect on the distribution of its isomerization products.

Anikeev V.I. , Sivcev V.P. , Il'ina I.V. , Korchagina D.V. , Statsenko O.B. , Volcho K.P. , Salakhutdinov N.F.
Transformations of several monoterpenoids in the presence of aldehydes in supercritical solvents
Russian Journal of Physical Chemistry A. 2013. V.87. N3. P.382-387. DOI: 10.1134/S0036024413030023 WOS Scopus РИНЦ

Опубликована online:	3 февр. 2013 г.
Опубликована в печати:	1 мар. 2013 г.

Web of science	WOS:000314407800008
Scopus	2-s2.0-84879657264
РИНЦ	20437382
OpenAlex	W2074440730