Perfluoro-3-ethyl-1,2,3,10b-tetrahydrofluoranthene

Perfluoro-3-ethyl-1,2,3,10b-tetrahydrofluoranthene Full article

Journal

MolBank
ISSN: 1422-8599

Output data

Year: 2024, Volume: 2024, Number: 3, Article number : M1842, Pages count : DOI: 10.3390/m1842

Tags

perfluorinated; fluoranthene; fluorene; antimony pentafluoride; 19F NMR; 19F–19F COSY; 19F–19F NOESY; variable-temperature NMR

Authors

Komarov Vladislav V. ¹ , Krasnov Vyacheslav I. ¹ , Karpov Victor M. ¹ , Parkhomenko Dmitriy A. ¹ , Mezhenkova Tatyana V. ¹

Affiliations

1	N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RAS

The title compound was synthesized from perfluoro-1-ethyltetralin and 1,2,3,4-tetrafluorobenzene under the action of antimony pentafluoride as a mixture of cis- and trans-isomers in a 71% isolated yield. The structure and cis-/trans-configuration of the isomers were determined by NMR (19F, 13C), 19F–19F COSY, and 19F–19F NOESY 2D NMR spectroscopy.

Komarov V.V. , Krasnov V.I. , Karpov V.M. , Parkhomenko D.A. , Mezhenkova T.V.
Perfluoro-3-ethyl-1,2,3,10b-tetrahydrofluoranthene
MolBank. 2024. V.2024. N3. M1842 . DOI: 10.3390/m1842

Submitted:	Jun 6, 2024
Accepted:	Jun 20, 2024
Published online:	Jun 25, 2024

OpenAlex

W4400127253