Synthesis of optically active Zn(II) complexes with thiosemicarbazones of (+)-camphor (L) and (-)-carvone (L-1). The crystal structures of L and [Zn(L)(2)Cl-2]

Synthesis of optically active Zn(II) complexes with thiosemicarbazones of (+)-camphor (L) and (-)-carvone (L-1). The crystal structures of L and [Zn(L)(2)Cl-2] Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2013, Volume: 39, Number: 6, Pages: 442-449 Pages count : 8 DOI: 10.1134/S1070328413050035

Authors

Kokina T.E. ^1,2 , Gorshkov N.B. ^2,3 , Glinskaya L.A. ¹ , Kurat'eva N.V. ¹ , Sheludyakova L.A. ¹ , Tkachev A.V. ^2,3 , Larionov S.V. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk, Russia

The optically active complexes [Zn(L)(2)Cl-2] (I) and [Zn(L-1)(2)Cl-2] (II) (L and L-1 are thiosemicar-bazones of (+)-camphor and (-)-carvone, respectively) were obtained. The crystal structures of L and complex I were determined by X-ray diffraction. The structure of L consists of hydrogen-bonded molecules united into chains. The crystal structure of complex I is built from mononuclear molecules. The coordination polyhedron of the Zn atom is a distorted tetrahedron Cl2S2. The molecule L functions as a monodentate ligand. According to data from IR spectroscopy, complex II is structurally similar to complex I.

Kokina T.E. , Gorshkov N.B. , Glinskaya L.A. , Kurat'eva N.V. , Sheludyakova L.A. , Tkachev A.V. , Larionov S.V.
Synthesis of optically active Zn(II) complexes with thiosemicarbazones of (+)-camphor (L) and (-)-carvone (L-1). The crystal structures of L and [Zn(L)(2)Cl-2]
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2013. V.39. N6. P.442-449. DOI: 10.1134/S1070328413050035 WOS Scopus РИНЦ

Published print:	Jun 1, 2013
Published online:	Jun 9, 2013

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