Synthesis of optically active Zn(II) complexes with thiosemicarbazones of (+)-camphor (L) and (-)-carvone (L-1). The crystal structures of L and [Zn(L)(2)Cl-2]

Synthesis of optically active Zn(II) complexes with thiosemicarbazones of (+)-camphor (L) and (-)-carvone (L-1). The crystal structures of L and [Zn(L)(2)Cl-2] Научная публикация

Журнал

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Вых. Данные

Год: 2013, Том: 39, Номер: 6, Страницы: 442-449 Страниц : 8 DOI: 10.1134/S1070328413050035

Авторы

Kokina T.E. ^1,2 , Gorshkov N.B. ^2,3 , Glinskaya L.A. ¹ , Kurat'eva N.V. ¹ , Sheludyakova L.A. ¹ , Tkachev A.V. ^2,3 , Larionov S.V. ¹

Организации

1	(Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk, Russia

The optically active complexes [Zn(L)(2)Cl-2] (I) and [Zn(L-1)(2)Cl-2] (II) (L and L-1 are thiosemicar-bazones of (+)-camphor and (-)-carvone, respectively) were obtained. The crystal structures of L and complex I were determined by X-ray diffraction. The structure of L consists of hydrogen-bonded molecules united into chains. The crystal structure of complex I is built from mononuclear molecules. The coordination polyhedron of the Zn atom is a distorted tetrahedron Cl2S2. The molecule L functions as a monodentate ligand. According to data from IR spectroscopy, complex II is structurally similar to complex I.

Kokina T.E. , Gorshkov N.B. , Glinskaya L.A. , Kurat'eva N.V. , Sheludyakova L.A. , Tkachev A.V. , Larionov S.V.
Synthesis of optically active Zn(II) complexes with thiosemicarbazones of (+)-camphor (L) and (-)-carvone (L-1). The crystal structures of L and [Zn(L)(2)Cl-2]
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2013. V.39. N6. P.442-449. DOI: 10.1134/S1070328413050035 WOS Scopus РИНЦ

Опубликована в печати:	1 июн. 2013 г.
Опубликована online:	9 июн. 2013 г.

Web of science	WOS:000320329800004
Scopus	2-s2.0-84879150169
РИНЦ	20438161
OpenAlex	W2462894327