Cyclization of citronellal in a supercritical solvent in a flow reactor in the presence of Al2O3

Cyclization of citronellal in a supercritical solvent in a flow reactor in the presence of Al2O3 Full article

Journal

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Output data

Year: 2012, Volume: 86, Number: 12, Pages: 1917-1919 Pages count : DOI: 10.1134/S0036024412120035

Tags

citronellal; isopulegol; cyclization; supercritical solvent; alumina

Authors

Anikeev V. I. ¹ , Il'ina I. V. ² , Volcho K. P. ² , Salakhutdinov N. F. ²

Affiliations

1	(Данные Web of science) Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

The reactivity of citronellal under supercritical solvent conditions in a flow reactor in the presence of Al2O3 is examined. It is shown that at 160A degrees C, the main transformation product of citronellal is isopulegol, and when the temperature is increased to 190A degrees C, they are monoterpenes with a para-menthane framework and myrcene.

Anikeev V.I. , Il'ina I.V. , Volcho K.P. , Salakhutdinov N.F.
Cyclization of citronellal in a supercritical solvent in a flow reactor in the presence of Al2O3
Russian Journal of Physical Chemistry A. 2012. V.86. N12. P.1917-1919. DOI: 10.1134/S0036024412120035 WOS Scopus РИНЦ

Аникеев В.И. , Ильина И.В. , Волчо К.П. , Салахутдинов Н.Ф.
Окисление -пинена кислородом воздуха в сверхкритической системе CO2 и этилацетата в присутствии комплексов CO(II)
Журнал физической химии (RUSS J PHYS CHEM A+). 2012. Т.86. №2. С.244. РИНЦ

Published online:	Oct 26, 2012
Published print:	Dec 1, 2012

Web of science	WOS:000310345600026
Scopus	2-s2.0-84869066381
Elibrary	20491585
OpenAlex	W2095441142