Cyclization of citronellal in a supercritical solvent in a flow reactor in the presence of Al2O3

Cyclization of citronellal in a supercritical solvent in a flow reactor in the presence of Al2O3 Научная публикация

Журнал

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Вых. Данные

Год: 2012, Том: 86, Номер: 12, Страницы: 1917-1919 Страниц : DOI: 10.1134/S0036024412120035

Ключевые слова

citronellal; isopulegol; cyclization; supercritical solvent; alumina

Авторы

Anikeev V. I. ¹ , Il'ina I. V. ² , Volcho K. P. ² , Salakhutdinov N. F. ²

Организации

1	(Данные Web of science) Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

The reactivity of citronellal under supercritical solvent conditions in a flow reactor in the presence of Al2O3 is examined. It is shown that at 160A degrees C, the main transformation product of citronellal is isopulegol, and when the temperature is increased to 190A degrees C, they are monoterpenes with a para-menthane framework and myrcene.

Anikeev V.I. , Il'ina I.V. , Volcho K.P. , Salakhutdinov N.F.
Cyclization of citronellal in a supercritical solvent in a flow reactor in the presence of Al2O3
Russian Journal of Physical Chemistry A. 2012. V.86. N12. P.1917-1919. DOI: 10.1134/S0036024412120035 WOS Scopus РИНЦ

Аникеев В.И. , Ильина И.В. , Волчо К.П. , Салахутдинов Н.Ф.
Окисление -пинена кислородом воздуха в сверхкритической системе CO2 и этилацетата в присутствии комплексов CO(II)
Журнал физической химии (RUSS J PHYS CHEM A+). 2012. Т.86. №2. С.244. РИНЦ

Опубликована online:	26 окт. 2012 г.
Опубликована в печати:	1 дек. 2012 г.

Web of science	WOS:000310345600026
Scopus	2-s2.0-84869066381
РИНЦ	20491585
OpenAlex	W2095441142