Crystal and molecular structure of the [Zn(HL)Cl]center dot EtOH compound, (H2L = chiral bis(menthane)propylenediaminodioxime) Full article
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Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2012, Volume: 53, Number: 6, Pages: 1111-1117 Pages count : 7 DOI: 10.1134/S0022476612060145 | ||||
| Tags | complex; solvate; zinc(II); bis(menthane) propylenediaminodioxime; structure | ||||
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Abstract:
The crystal structure of a solvate [Zn(HL)Cl]center dot EtOH is determined by single crystal X-ray crystallography (150 K, Bruker X8 Apex CCD autodiffractometer, MoK (alpha) radiation). The crystals are triclinic, unit cell parameters are: a = 7.4755(4) , b = 13.9701(11) , c = 14.4593(19) , alpha = 82.277(2)A degrees, beta = 75.410(2)A degrees, gamma = 75.356(1)A degrees, space group P1. The structure of the solvate contains two crystallographically independent complex [Zn(HL)Cl] molecules and two non-coordinated ethanol molecules. In each of the molecules, Zn2+ ions coordinate N atoms of tetradentate chelating ligands HL- and a Cl atom. ClN4 polyhedra have a distorted tetragonal pyramidal geometry. EtOH molecules make H-bonds with the complex molecules, thus facilitating the formation of chains along the x axis.
Cite:
Glinskaya L.A.
, Savel'eva Z.A.
, Bizyaev S.N.
, Tkachev A.V.
, Larionov S.V.
Crystal and molecular structure of the [Zn(HL)Cl]center dot EtOH compound, (H2L = chiral bis(menthane)propylenediaminodioxime)
Journal of Structural Chemistry. 2012. V.53. N6. P.1111-1117. DOI: 10.1134/S0022476612060145 WOS Scopus РИНЦ
Crystal and molecular structure of the [Zn(HL)Cl]center dot EtOH compound, (H2L = chiral bis(menthane)propylenediaminodioxime)
Journal of Structural Chemistry. 2012. V.53. N6. P.1111-1117. DOI: 10.1134/S0022476612060145 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Глинская Л.А.
, Савельева З.А.
, Бизяев С.Н.
, Ткачев А.В.
, Ларионов С.В.
Кристаллическая и молекулярная структура соединения [zn(hl)cl]×etoh, (н 2l = хиральный бис(ментановый) пропилендиаминодиоксим)
Журнал структурной химии (J STRUCT CHEM+). 2012. Т.53. №6. С.1135-1140. РИНЦ
Кристаллическая и молекулярная структура соединения [zn(hl)cl]×etoh, (н 2l = хиральный бис(ментановый) пропилендиаминодиоксим)
Журнал структурной химии (J STRUCT CHEM+). 2012. Т.53. №6. С.1135-1140. РИНЦ
Dates:
| Published print: | Nov 1, 2012 |
| Published online: | Feb 2, 2013 |
Identifiers:
| Web of science | WOS:000314365600014 |
| Scopus | 2-s2.0-84873354498 |
| Elibrary | 20483224 |
| OpenAlex | W2463380152 |