Crystal and molecular structure of the [Zn(HL)Cl]center dot EtOH compound, (H2L = chiral bis(menthane)propylenediaminodioxime)

Crystal and molecular structure of the [Zn(HL)Cl]center dot EtOH compound, (H2L = chiral bis(menthane)propylenediaminodioxime) Научная публикация

Журнал

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Вых. Данные

Год: 2012, Том: 53, Номер: 6, Страницы: 1111-1117 Страниц : 7 DOI: 10.1134/S0022476612060145

Ключевые слова

complex; solvate; zinc(II); bis(menthane) propylenediaminodioxime; structure

Авторы

Glinskaya L.A. ¹ , Savel'eva Z.A. ¹ , Bizyaev S.N. ² , Tkachev A.V. ² , Larionov S.V. ¹

Организации

1	(Данные Web of science) Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia
2	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Inst Organ Chem, Siberian Div, Novosibirsk, Russia

The crystal structure of a solvate [Zn(HL)Cl]center dot EtOH is determined by single crystal X-ray crystallography (150 K, Bruker X8 Apex CCD autodiffractometer, MoK (alpha) radiation). The crystals are triclinic, unit cell parameters are: a = 7.4755(4) , b = 13.9701(11) , c = 14.4593(19) , alpha = 82.277(2)A degrees, beta = 75.410(2)A degrees, gamma = 75.356(1)A degrees, space group P1. The structure of the solvate contains two crystallographically independent complex [Zn(HL)Cl] molecules and two non-coordinated ethanol molecules. In each of the molecules, Zn2+ ions coordinate N atoms of tetradentate chelating ligands HL- and a Cl atom. ClN4 polyhedra have a distorted tetragonal pyramidal geometry. EtOH molecules make H-bonds with the complex molecules, thus facilitating the formation of chains along the x axis.

Glinskaya L.A. , Savel'eva Z.A. , Bizyaev S.N. , Tkachev A.V. , Larionov S.V.
Crystal and molecular structure of the [Zn(HL)Cl]center dot EtOH compound, (H2L = chiral bis(menthane)propylenediaminodioxime)
Journal of Structural Chemistry. 2012. V.53. N6. P.1111-1117. DOI: 10.1134/S0022476612060145 WOS Scopus РИНЦ

Глинская Л.А. , Савельева З.А. , Бизяев С.Н. , Ткачев А.В. , Ларионов С.В.
Кристаллическая и молекулярная структура соединения [zn(hl)cl]×etoh, (н 2l = хиральный бис(ментановый) пропилендиаминодиоксим)
Журнал структурной химии (J STRUCT CHEM+). 2012. Т.53. №6. С.1135-1140. РИНЦ

Опубликована в печати:	1 нояб. 2012 г.
Опубликована online:	2 февр. 2013 г.

Web of science	WOS:000314365600014
Scopus	2-s2.0-84873354498
РИНЦ	20483224
OpenAlex	W2463380152