One-Pot Atom-Economic Synthesis of Thioselenophosphinates via a New Multicomponent Reaction of Secondary Phosphanes with Elemental Sulfur, Selenium, and Amines Full article
Journal |
European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690 |
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Output data | Year: 2010, Volume: 2010, Number: 32, Pages: 6157-6160 Pages count : DOI: 10.1002/ejoc.201001189 | ||||
Tags | Phosphanes; Sulfur; Selenium; Amines; Multicomponent reactions | ||||
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Abstract:
The multicomponent reaction between secondary phosphanes R2PH (R = Ph, arylalkyl, hetarylalkyl), elemental sulfur, selenium, and primary, secondary, or tertiary amines to afford the corresponding mono-, di-, and trialkylammonium thioselenophosphinates has been discovered. The atom-economic reaction proceeds under mild conditions (ethanol/toluene, 40-70 degrees C, 40 min) to give the target alkylammonium thioselenophosphinates in high yields (up to 94%).
Cite:
Artem'ev A.V.
, Gusarova N.K.
, Malysheva S.F.
, Mamatyuk V.I.
, Gatilov Y.V.
, Ushakov I.A.
, Trofimov B.A.
One-Pot Atom-Economic Synthesis of Thioselenophosphinates via a New Multicomponent Reaction of Secondary Phosphanes with Elemental Sulfur, Selenium, and Amines
European Journal of Organic Chemistry. 2010. V.2010. N32. P.6157-6160. DOI: 10.1002/ejoc.201001189 WOS Scopus РИНЦ
One-Pot Atom-Economic Synthesis of Thioselenophosphinates via a New Multicomponent Reaction of Secondary Phosphanes with Elemental Sulfur, Selenium, and Amines
European Journal of Organic Chemistry. 2010. V.2010. N32. P.6157-6160. DOI: 10.1002/ejoc.201001189 WOS Scopus РИНЦ
Dates:
Published online: | Oct 11, 2010 |
Published print: | Nov 1, 2010 |
Identifiers:
Web of science | WOS:000285041500005 |
Scopus | 2-s2.0-78249272919 |
Elibrary | 16697762 |
OpenAlex | W2023525548 |