Nitrosonium Complexes of Triptycene Full article
Journal |
Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
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Output data | Year: 2009, Volume: 45, Number: 9, Pages: 1344-1348 Pages count : 5 DOI: 10.1134/S1070428009090061 | ||
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Abstract:
According to the H-1 and C-13 NMR data, triptycene reacts with nitrosonium tetrachloroaluminate to form positively charged pi-complexes with one and two nitrosonium ions, which are rapidly (on the NMR time scale) converted into each other. DFT quantum-chemical calculations with Lambda 02 basis set indicated higher stability of singly charged complexes relative to doubly charged. Addition of three nitrosonium ions to triptycene molecule is unfavorable from the energy viewpoint.
Cite:
Borodkin G.I.
, Elanov I.R.
, Andreev R.V.
, Shubin V.G.
Nitrosonium Complexes of Triptycene
Russian Journal of Organic Chemistry. 2009. V.45. N9. P.1344-1348. DOI: 10.1134/S1070428009090061 WOS Scopus РИНЦ
Nitrosonium Complexes of Triptycene
Russian Journal of Organic Chemistry. 2009. V.45. N9. P.1344-1348. DOI: 10.1134/S1070428009090061 WOS Scopus РИНЦ
Dates:
Published print: | Sep 1, 2009 |
Published online: | Oct 13, 2009 |
Identifiers:
Web of science | WOS:000270744600006 |
Scopus | 2-s2.0-84877100562 |
Elibrary | 21894286 |
OpenAlex | W2018597837 |