Nitrosonium Complexes of Triptycene Научная публикация
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Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
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| Вых. Данные | Год: 2009, Том: 45, Номер: 9, Страницы: 1344-1348 Страниц : 5 DOI: 10.1134/S1070428009090061 | ||
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Реферат:
According to the H-1 and C-13 NMR data, triptycene reacts with nitrosonium tetrachloroaluminate to form positively charged pi-complexes with one and two nitrosonium ions, which are rapidly (on the NMR time scale) converted into each other. DFT quantum-chemical calculations with Lambda 02 basis set indicated higher stability of singly charged complexes relative to doubly charged. Addition of three nitrosonium ions to triptycene molecule is unfavorable from the energy viewpoint.
Библиографическая ссылка:
Borodkin G.I.
, Elanov I.R.
, Andreev R.V.
, Shubin V.G.
Nitrosonium Complexes of Triptycene
Russian Journal of Organic Chemistry. 2009. V.45. N9. P.1344-1348. DOI: 10.1134/S1070428009090061 WOS Scopus РИНЦ
Nitrosonium Complexes of Triptycene
Russian Journal of Organic Chemistry. 2009. V.45. N9. P.1344-1348. DOI: 10.1134/S1070428009090061 WOS Scopus РИНЦ
Даты:
| Опубликована в печати: | 1 сент. 2009 г. |
| Опубликована online: | 13 окт. 2009 г. |
Идентификаторы:
| Web of science | WOS:000270744600006 |
| Scopus | 2-s2.0-84877100562 |
| РИНЦ | 21894286 |
| OpenAlex | W2018597837 |