Synthesis, structure, and luminescence properties of complex ZnLCl2 (L is 2-(3,5-dimethylpyrazol-1-yl)-4-methylquinoline)

Synthesis, structure, and luminescence properties of complex ZnLCl2 (L is 2-(3,5-dimethylpyrazol-1-yl)-4-methylquinoline) Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 2009, Volume: 58, Number: 9, Pages: 1837-1840 Pages count : 4 DOI: 10.1007/s11172-009-0250-9

Tags

zinc(II) complex; synthesis; X-ray diffraction analysis; luminescence

Authors

Savel'eva Z.A. ¹ , Popov S.A. ² , Klevtsova R.F. ¹ , Glinskaya L.A. ¹ , Uskov E.M. ¹ , Tkachev A.V. ² , Larionova S.V. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, AV Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

A complex ZnLCl2 (L is 2-(3,5-dimethylpyrazol-1-yl)-4-methylquinoline) was synthesized. According to X-ray diffraction data, the Zn2+ ions in mononuclear molecules of the obtained complex coordinate two N atoms of the bidentate chelating ligand L and two Cl atoms. The coordination polyhedron Cl2N2 represents a distorted tetrahedron. In solid state at 300 K, the ligand L exhibits weak photoluminescence in the visible spectral range. The complex ZnLCl2 exhibits bright blue photoluminescence.

Savel'eva Z.A. , Popov S.A. , Klevtsova R.F. , Glinskaya L.A. , Uskov E.M. , Tkachev A.V. , Larionova S.V.
Synthesis, structure, and luminescence properties of complex ZnLCl2 (L is 2-(3,5-dimethylpyrazol-1-yl)-4-methylquinoline)
Russian Chemical Bulletin. 2009. V.58. N9. P.1837-1840. DOI: 10.1007/s11172-009-0250-9 WOS Scopus РИНЦ

Published print:	Sep 1, 2009
Published online:	Aug 20, 2010

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