Synthesis, structure, and luminescence properties of complex ZnLCl2 (L is 2-(3,5-dimethylpyrazol-1-yl)-4-methylquinoline)

Synthesis, structure, and luminescence properties of complex ZnLCl2 (L is 2-(3,5-dimethylpyrazol-1-yl)-4-methylquinoline) Научная публикация

Журнал

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Вых. Данные

Год: 2009, Том: 58, Номер: 9, Страницы: 1837-1840 Страниц : 4 DOI: 10.1007/s11172-009-0250-9

Ключевые слова

zinc(II) complex; synthesis; X-ray diffraction analysis; luminescence

Авторы

Savel'eva Z.A. ¹ , Popov S.A. ² , Klevtsova R.F. ¹ , Glinskaya L.A. ¹ , Uskov E.M. ¹ , Tkachev A.V. ² , Larionova S.V. ¹

Организации

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, AV Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

A complex ZnLCl2 (L is 2-(3,5-dimethylpyrazol-1-yl)-4-methylquinoline) was synthesized. According to X-ray diffraction data, the Zn2+ ions in mononuclear molecules of the obtained complex coordinate two N atoms of the bidentate chelating ligand L and two Cl atoms. The coordination polyhedron Cl2N2 represents a distorted tetrahedron. In solid state at 300 K, the ligand L exhibits weak photoluminescence in the visible spectral range. The complex ZnLCl2 exhibits bright blue photoluminescence.

Savel'eva Z.A. , Popov S.A. , Klevtsova R.F. , Glinskaya L.A. , Uskov E.M. , Tkachev A.V. , Larionova S.V.
Synthesis, structure, and luminescence properties of complex ZnLCl2 (L is 2-(3,5-dimethylpyrazol-1-yl)-4-methylquinoline)
Russian Chemical Bulletin. 2009. V.58. N9. P.1837-1840. DOI: 10.1007/s11172-009-0250-9 WOS Scopus РИНЦ

Опубликована в печати:	1 сент. 2009 г.
Опубликована online:	20 авг. 2010 г.

Web of science	WOS:000283500400009
Scopus	2-s2.0-77956578408
РИНЦ	15304292
OpenAlex	W1965250149